Photocatalytic late-stage C–H functionalization

P Bellotti, HM Huang, T Faber, F Glorius - Chemical Reviews, 2023 - ACS Publications
The emergence of modern photocatalysis, characterized by mildness and selectivity, has
significantly spurred innovative late-stage C–H functionalization approaches that make use …

Electrochemical late-stage functionalization

Y Wang, S Dana, H Long, Y Xu, Y Li… - Chemical …, 2023 - ACS Publications
Late-stage functionalization (LSF) constitutes a powerful strategy for the assembly or
diversification of novel molecular entities with improved physicochemical or biological …

Supramolecular coordination cages for artificial photosynthesis and synthetic photocatalysis

R Ham, CJ Nielsen, S Pullen, JNH Reek - Chemical Reviews, 2023 - ACS Publications
Because sunlight is the most abundant energy source on earth, it has huge potential for
practical applications ranging from sustainable energy supply to light driven chemistry. From …

Photoactive copper complexes: properties and applications

J Beaudelot, S Oger, S Perusko, TA Phan… - Chemical …, 2022 - ACS Publications
Photocatalyzed and photosensitized chemical processes have seen growing interest
recently and have become among the most active areas of chemical research, notably due …

Radical NHC catalysis

K Liu, M Schwenzer, A Studer - ACS Catalysis, 2022 - ACS Publications
Radical/radical cross-coupling reactions represent an efficient and straightforward approach
for the construction of chemical bonds and accordingly have drawn increasing attention over …

Late-stage C–H functionalization of azines

CM Josephitis, HMH Nguyen, A McNally - Chemical reviews, 2023 - ACS Publications
Azines, such as pyridines, quinolines, pyrimidines, and pyridazines, are widespread
components of pharmaceuticals. Their occurrence derives from a suite of physiochemical …

Enantioselective radical reactions using chiral catalysts

S Mondal, F Dumur, D Gigmes, MP Sibi… - Chemical …, 2022 - ACS Publications
Benefiting from the impressive increase in fundamental knowledge, the last 20 years have
shown a continuous burst of new ideas and consequently a plethora of new catalytic …

Strain-release photocatalysis

P Bellotti, F Glorius - Journal of the American Chemical Society, 2023 - ACS Publications
The concept of strain in organic compounds is as old as modern organic chemistry and was
initially introduced to justify the synthetic setbacks along the synthesis of small ring systems …

Carboxylic acids as adaptive functional groups in metallaphotoredox catalysis

SB Beil, TQ Chen, NE Intermaggio… - Accounts of chemical …, 2022 - ACS Publications
Conspectus The development of palladium-catalyzed cross-coupling methods for the
activation of C (sp2)–Br bonds facilitated access to arene-rich molecules, enabling a …

Ligand‐to‐metal charge transfer (LMCT) photochemistry at 3d‐metal complexes: an emerging tool for sustainable organic synthesis

F Juliá - ChemCatChem, 2022 - Wiley Online Library
Despite the rich photochemistry of 3d‐metal complexes, the utilization of excited‐state
reactivity of these compounds in organic synthesis has been historically overlooked. The …