Enhanced fluoride uptake by layered double hydroxides under alkaline conditions: Solid-state NMR evidence of the role of surface> MgOH sites
C Ren, M Zhou, Z Liu, L Liang, X Li, X Lu… - Environmental …, 2021 - ACS Publications
Layered double hydroxides (LDHs) are potential low-cost filter materials for use in fluoride
removal from drinking water, but molecular-scale defluoridation mechanisms are lacking. In …
removal from drinking water, but molecular-scale defluoridation mechanisms are lacking. In …
Insights into the Micro-Structure-Transport Relationships of the Fluoride-Ion Conductor t-BaSnF4 Synthesized by Spark Plasma Sintering
The tetragonal ordered form of BaSnF4 is of particular interest, as its ionic conductivity is
high enough to enable its uses as an electrolyte in all-solid-state fluoride-ion batteries …
high enough to enable its uses as an electrolyte in all-solid-state fluoride-ion batteries …
Dramatic Enhancement of Rare-Earth Metal–Organic Framework Stability Via Metal Cluster Fluorination
Rare-earth polynuclear metal–organic frameworks (RE-MOFs) have demonstrated high
durability for caustic acid gas adsorption and separation based on gas adsorption to the …
durability for caustic acid gas adsorption and separation based on gas adsorption to the …
Correlated Anion Disorder in Heteroanionic Cubic TiOF2
Resolving anion configurations in heteroanionic materials is crucial for understanding and
controlling their properties. For anion-disordered oxyfluorides, conventional Bragg diffraction …
controlling their properties. For anion-disordered oxyfluorides, conventional Bragg diffraction …
Exploring the Sm1–xCaxF3–x Tysonite Solid Solution as a Solid-State Electrolyte: Relationships between Structural Features and F– Ionic Conductivity
B Dieudonné, J Chable, F Mauvy… - The Journal of …, 2015 - ACS Publications
Pure tysonite Sm1–x Ca x F3–x solid solutions for 0.05≤ x≤ 0.17 have been prepared by
the solid-state route. For the first time, the partial Sm1–x Ca x F3–x solid solution is …
the solid-state route. For the first time, the partial Sm1–x Ca x F3–x solid solution is …
The key role of the composition and structural features in fluoride ion conductivity in tysonite Ce 1− x Sr x F 3− x solid solutions
Pure tysonite-type Ce1− xSrxF3− x solid solutions for 0≤ x< 0.15 were prepared by a solid-
state route at 900° C. The cell parameters follow Vegard's laws for 0≤ x≤ 0.10 and the …
state route at 900° C. The cell parameters follow Vegard's laws for 0≤ x≤ 0.10 and the …
Machine-learning-assisted synthesis of polar racemates
Racemates have recently received attention as nonlinear optical and piezoelectric materials.
Here, a machine-learning-assisted composition space approach was applied to synthesize …
Here, a machine-learning-assisted composition space approach was applied to synthesize …
Structural Modeling of O/F Correlated Disorder in TaOF3 and NbOF3–x(OH)x by Coupling Solid-State NMR and DFT Calculations
The structure of MOF3 (M= Nb, Ta) compounds was precisely modeled by combining
powder X-ray diffraction, solid-state NMR spectroscopy, and semiempirical dispersion …
powder X-ray diffraction, solid-state NMR spectroscopy, and semiempirical dispersion …
Solid State Fluorination on the Minute Scale: Synthesis of WO3−xFx with Photocatalytic Activity
Solid state reactions are notoriously slow, because the rate‐limiting step is diffusion of atoms
or ions through reactant, intermediate, and product crystalline phases. This requires days or …
or ions through reactant, intermediate, and product crystalline phases. This requires days or …
NMR parameters in column 13 metal fluoride compounds (AlF3, GaF3, InF3 and TlF) from first principle calculations
The relationship between the experimental 19 F isotropic chemical shift and the 19 F
isotropic shielding calculated using the gauge including projector augmented-wave …
isotropic shielding calculated using the gauge including projector augmented-wave …