Organic synthesis with the most abundant transition metal–iron: from rust to multitasking catalysts

S Rana, JP Biswas, S Paul, A Paik… - Chemical Society Reviews, 2021 - pubs.rsc.org
In industries and academic laboratories, several late transition metal-catalyzed prerequisite
reactions are widely performed during single and multistep synthesis. However, besides the …

Iron catalysis in organic synthesis

I Bauer, HJ Knölker - Chemical reviews, 2015 - ACS Publications
The present review “Iron Catalysis in Organic Synthesis” covers the literature until the end of
June 2014 and represents a comprehensive update of a previous article published by Bolm …

Direct Nucleophilic SN1‐Type Reactions of Alcohols

E Emer, R Sinisi, MG Capdevila… - European Journal of …, 2011 - Wiley Online Library
Abstract In 2005, the ACS Green Chemistry Institute (GCI) and the global pharmaceutical
corporations developed the ACS GCI Pharmaceutical Roundtable to encourage the …

Alcohols as Substrates in Transition-Metal-Catalyzed Arylation, Alkylation, and Related Reactions

A Cook, SG Newman - Chemical Reviews, 2024 - ACS Publications
Alcohols are abundant and attractive feedstock molecules for organic synthesis. Many
methods for their functionalization require them to first be converted into a more activated …

FeCl3-catalyzed Ritter reaction. Synthesis of amides

B Anxionnat, A Guerinot, S Reymond, J Cossy - Tetrahedron Letters, 2009 - Elsevier
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Iron (III) Chloride‐Catalyzed Direct Sulfonylation of Alcohols with Sodium Arenesulfinates

MA Reddy, PS Reddy… - Advanced Synthesis & …, 2010 - Wiley Online Library
A new protocol for the direct sulfonylation of benzylic, allylic and homoallylic alcohols with
sodium arenesulfinates is described by using iron (III) chloride as a catalyst and …

Sustainable hydration of alkynes promoted by first row transition metal complexes. Background, highlights and perspectives

R Salvio, M Bassetti - Inorganica Chimica Acta, 2021 - Elsevier
The review describes the state of the art in hydration reactions of alkynes by direct or indirect
catalysis of first row transition metal complexes, covering mostly the literature of the last …

Iron-catalyzed stereospecific olefin synthesis by direct coupling of alcohols and alkenes with alcohols

ZQ Liu, Y Zhang, L Zhao, Z Li, J Wang, H Li… - Organic Letters, 2011 - ACS Publications
An efficient Fe (III)-catalyzed direct coupling of alkenes with alcohols and cross-coupling of
alcohols with alcohols to give the corresponding substituted (E)-alkenes stereospecifically is …

Recent uses of iron catalysts in organic reactions

Liu - Current Organic Chemistry, 2010 - benthamdirect.com
Iron catalysts are extensively used in organic reactions in recent years since iron is one of
the most abundant metals on earth, consequently one of the most inexpensive, and …

Cyclopentanone as a cation-stabilizing electron-pair donor in the calcium-catalyzed intermolecular carbohydroxylation of alkynes

T Stopka, M Niggemann - Organic letters, 2015 - ACS Publications
Although they have been used as reactivity-controlling additives in cationic polymerizations
for decades, Lewis basic “electron pair donor”(ED) compounds were never used for the …