Manganese (III) Nitrate Complexes as Bench-Stable Powerful Oxidants

A Saju, MR Crawley, SN MacMillan… - Journal of the American …, 2024 - ACS Publications
We report herein a convenient one-pot synthesis for the shelf-stable molecular complex [Mn
(NO3) 3 (OPPh3) 2](2) and describe the properties that make it a powerful and selective one …

Topology-Directed Synthesis of Helical Phosphoniums with High Diradical Character and Polar-Dependent Electron Transfer

B Yang, S Yan, S Ban, Y Zhang, H Ma… - Chemistry of …, 2024 - ACS Publications
Molecular topology synthesis of polycyclic aromatic hydrocarbons (PAHs) with diradical
character takes root in intramolecular coupling breakthrough. Herein, we report selective Mn …

Heteromultimetallic Platform for Enhanced C–H Bond Activation: Aluminum-Incorporated Dicopper Complex Mimicking Cu-ZSM-5 Structure and Oxidative Reactivity

YJ Son, D Kim, JW Park, K Ko, Y Yu… - Journal of the American …, 2024 - ACS Publications
Bimetallic complexes have sparked interest across various chemical disciplines, driving
advancements in research. Recent advancements in this field have shed light on complex …

NMR spectroscopic investigations of transition metal complexes in organometallic and bioinorganic chemistry

J Shin, MH Lim, J Han - Bulletin of the Korean Chemical Society, 2024 - Wiley Online Library
The field of coordination chemistry has evolved to intersect with organic chemistry and
biochemistry, giving rise to the disciplines of organometallic and bioinorganic chemistry …

High‐Valent Cobalt‐Difluoride in Oxidative Fluorination of Saturated Hydrocarbons

AR McDonald, A Das, B Twamley, OR Kelly… - Angewandte Chemie … - Wiley Online Library
The heme paradigm where Fe= O acts as the C–H oxidant and Fe–OH rebounds with the
formed carbon‐centered radical guides the design of the prototypical synthetic hydroxylation …