Structural chemistry of giant metal based supramolecules

AV Virovets, E Peresypkina, M Scheer - Chemical Reviews, 2021 - ACS Publications
The review presents a bird-eye view on the state of research in the field of giant
nonbiological discrete metal complexes and ions of nanometer size, which are structurally …

Helicate lanthanide complexes: The luminescent elements

M Hasegawa, H Ohmagari - Chemistry Letters, 2020 - academic.oup.com
Luminescent lanthanide (Ln) complexes based on chelate effects will be introduced using a
series of hexadentate bipyridine derivatives as their ligand moieties. The molecules form a …

Dynamic covalent self-sorting and kinetic switching processes in two cyclic orders: Macrocycles and macrobicyclic cages

Z Yang, JM Lehn - Journal of the American Chemical Society, 2020 - ACS Publications
Dynamic covalent component self-sorting processes have been investigated for constituents
of different cyclic orders, macrocycles and macrobicyclic cages based on multiple reversible …

[M8L4]8+-Type Squares Self-Assembled by Dipalladium Corners and Bridging Aromatic Dipyrazole Ligands for Iodine Capture

MY Zhou, ZS Yu, W Deng, HL Lu, XF Niu… - Inorganic …, 2023 - ACS Publications
Square-like metallamacrocyclic palladium (II) complexes [M8L4] 8+(1–7) were synthesized
by reacting aromatic dipyrazole ligands (H2L1–H2L3 with pyromellitic arylimide-, 1, 4, 5, 8 …

Rotaxanating metallo-supramolecular nano-cylinder helicates to switch DNA junction binding

CAJ Hooper, L Cardo, JS Craig, L Melidis… - Journal of the …, 2020 - ACS Publications
A class of rotaxane is created, not by encapsulating a conventional linear thread, but rather
by wrapping a large cucurbit [10] uril macrocycle about a three-dimensional, cylindrical …

Switching dual catalysis without molecular switch: Using a multicomponent information system for reversible reconfiguration of catalytic machinery

A Goswami, T Paululat, M Schmittel - Journal of the American …, 2019 - ACS Publications
Different from the current paradigms of chemistry, a switchable catalytic system is presented
that does not rely on a molecular switch in different toggling states but on a smart seven …

Transient self-assembly of metal–organic complexes

JF Ayme, B Bruchmann, L Karmazin, N Kyritsakas - Chemical Science, 2023 - pubs.rsc.org
Implementing transient processes in networks of dynamic molecules holds great promise for
developing new functional behaviours. Here we report that trichloroacetic acid can be used …

Pattern generation and information transfer through a liquid/liquid interface in 3D constitutional dynamic networks of imine ligands in response to metal cation effectors

A Osypenko, S Dhers, JM Lehn - Journal of the American …, 2019 - ACS Publications
The immense discriminative capacity of the human olfactory chemosensory systems relies
on the generation of a combinatorial signal in response to the interaction of a particular …

Simultaneous generation of a [2× 2] grid-like complex and a linear double helicate: a three-level self-sorting process

JF Ayme, JM Lehn, C Bailly… - Journal of the American …, 2020 - ACS Publications
Two constitutional dynamic libraries (CDLs)—each containing two amines, two dialdehydes,
and two metal salts—have been found to self-sort, generating two pairs of imine-based …

Self-sorting of two imine-based metal complexes: balancing kinetics and thermodynamics in constitutional dynamic networks

JF Ayme, JM Lehn - Chemical Science, 2020 - pubs.rsc.org
A major hurdle in the development of complex constitutional dynamic networks (CDNs) is
the lack of strategies to simultaneously control the output of two (or more) interconnected …