Photoactive Metal-to-Ligand Charge Transfer Excited States in 3d6 Complexes with Cr0, MnI, FeII, and CoIII
Many coordination complexes and organometallic compounds with the 4d6 and 5d6
valence electron configurations have outstanding photophysical and photochemical …
valence electron configurations have outstanding photophysical and photochemical …
Ligand‐to‐metal charge transfer (LMCT) photochemistry at 3d‐metal complexes: an emerging tool for sustainable organic synthesis
F Juliá - ChemCatChem, 2022 - Wiley Online Library
Despite the rich photochemistry of 3d‐metal complexes, the utilization of excited‐state
reactivity of these compounds in organic synthesis has been historically overlooked. The …
reactivity of these compounds in organic synthesis has been historically overlooked. The …
The mechanism of visible light-induced C–C cross-coupling by C sp3–H bond activation
Csp3–C cross-coupling by activating Csp3–H bonds is a dream reaction for the chemical
community, and visible light-induced transition metal-catalysis under mild reaction …
community, and visible light-induced transition metal-catalysis under mild reaction …
Overcoming photochemical limitations in metallaphotoredox catalysis: red-light-driven C–N cross-coupling
SL Goldschmid, NE Soon Tay, CL Joe… - Journal of the …, 2022 - ACS Publications
Aryl amination is an essential transformation for medicinal, process, and materials chemistry.
In addition to classic Buchwald–Hartwig amination conditions, blue-light-driven …
In addition to classic Buchwald–Hartwig amination conditions, blue-light-driven …
Covalent‐Bonding Oxidation Group and Titanium Cluster to Synthesize a Porous Crystalline Catalyst for Selective Photo‐Oxidation Biomass Valorization
JN Chang, Q Li, Y Yan, JW Shi, J Zhou… - Angewandte …, 2022 - Wiley Online Library
The selective photo‐oxidation of biomass‐derived 5‐hydroxymethylfurfural (HMF) to 2, 5‐
furandicarboxylic acid (FDCA) is important due to its substitute‐role in polyester‐fabrication …
furandicarboxylic acid (FDCA) is important due to its substitute‐role in polyester‐fabrication …
Molecular Design Principles to Elongate the Metal-to-Ligand Charge Transfer Excited-State Lifetimes of Square-Planar Nickel (II) Complexes
Square-planar NiII complexes and their electronically excited states play key roles in cross-
coupling catalysis and could offer new opportunities to complement well-known …
coupling catalysis and could offer new opportunities to complement well-known …
Photochemical synthesis of anilines via Ni-catalyzed coupling of aryl halides with ammonium salts
G Song, DZ Nong, Q Li, Y Yan, G Li, J Fan… - ACS …, 2022 - ACS Publications
Easy, efficient, and economic synthesis of anilines remains an important challenge in
synthetic chemistry. In this study, a Ni (OAc) 2-bipyridine complex is shown to readily …
synthetic chemistry. In this study, a Ni (OAc) 2-bipyridine complex is shown to readily …
Zinc (II) complexes with triplet charge-transfer excited states enabling energy-transfer catalysis, photoinduced electron transfer, and upconversion
Many CuI complexes have luminescent triplet charge-transfer excited states with diverse
applications in photophysics and photochemistry, but for isoelectronic ZnII compounds, this …
applications in photophysics and photochemistry, but for isoelectronic ZnII compounds, this …
Nickel (II) Analogues of Phosphorescent Platinum (II) Complexes with Picosecond Excited‐State Decay
Square‐planar NiII complexes are interesting as cheaper and more sustainable alternatives
to PtII luminophores widely used in lighting and photocatalysis. We investigated the excited …
to PtII luminophores widely used in lighting and photocatalysis. We investigated the excited …
Flexible Crystal Heterojunctions of Low-Dimensional Organic Metal Halides Enabling Color-Tunable Space-Resolved Optical Waveguides
Y Lin, S Liu, D Yan - Research, 2023 - spj.science.org
Molecular luminescent materials with optical waveguide have wide application prospects in
light-emitting diodes, sensors, and logic gates. However, the majority of traditional optical …
light-emitting diodes, sensors, and logic gates. However, the majority of traditional optical …