Endogenous photosensitizers in human skin
Endogenous photosensitizers play a critical role in both beneficial and harmful light-induced
transformations in biological systems. Understanding their mode of action is essential for …
transformations in biological systems. Understanding their mode of action is essential for …
Alkane functionalization: Recent advances
NR Conceição, KT Mahmudov, MFCG da Silva… - Coordination Chemistry …, 2025 - Elsevier
Despite the progress of alternative/renewable energy technologies (solar, wind,
hydroelectric, geothermal, nuclear, hydrogen, bio, tidal and wave), still the fossil raw …
hydroelectric, geothermal, nuclear, hydrogen, bio, tidal and wave), still the fossil raw …
Scalable electrochemical aerobic oxygenation of indoles to isatins without electron transfer mediators by merging with an oxygen reduction reaction
W Zhuang, J Zhang, C Ma, JS Wright, X Zhang… - Organic …, 2022 - ACS Publications
An approach to electrochemical oxygenation of indoles leading to isatins was developed by
merging with a complementary cathode oxygen reduction reaction. The features of this …
merging with a complementary cathode oxygen reduction reaction. The features of this …
Chemoselective decarboxylative oxygenation of carboxylic acids to access ketones, aldehydes, and peroxides
R Guan, G Chen, EL Bennett, Z Huang, J Xiao - Organic Letters, 2023 - ACS Publications
Reported here is a photocatalytic strategy for the chemoselective decarboxylative
oxygenation of carboxylic acids using Ce (III) catalysts and O2 as the oxidant. By simply …
oxygenation of carboxylic acids using Ce (III) catalysts and O2 as the oxidant. By simply …
Creating, Preserving, and Directing Carboxylate Radicals in Ni-Catalyzed C(sp3)–H Acyloxylation of Ethers, Ketones, and Alkanes with Diacyl Peroxides
The reaction of Ni (II) acetate with diacyl peroxides produces high-valence Ni-species
capable of catalytic oxidative acyloxylation of C (sp3)–H bonds in ethers, ketones, and …
capable of catalytic oxidative acyloxylation of C (sp3)–H bonds in ethers, ketones, and …
Synergism of primary and secondary interactions in a crystalline hydrogen peroxide complex with tin
AG Medvedev, PA Egorov, AA Mikhaylov… - Nature …, 2024 - nature.com
Despite the significance of H2O2-metal adducts in catalysis, materials science and
biotechnology, the nature of the interactions between H2O2 and metal cations remains …
biotechnology, the nature of the interactions between H2O2 and metal cations remains …
Electrochemical Generation of Peroxy Radicals and Subsequent Peroxidation of 1, 3-Dicarbonyls in an Undivided Cell
OV Bityukov, KV Skokova, VA Vil', GI Nikishin… - Organic …, 2023 - ACS Publications
The generation of peroxy radicals from hydroperoxides with subsequent selective
peroxidation of 1, 3-dicarbonyls in an undivided electrochemical cell under constant current …
peroxidation of 1, 3-dicarbonyls in an undivided electrochemical cell under constant current …
Peroxide-Selective Reduction of O2 at Redox-Inactive Rare-Earth(III) Triflates Generates an Ambiphilic Peroxide
Metal peroxides are key species involved in a range of critical biological and synthetic
processes. Rare-earth (group III and the lanthanides; Sc, Y, La–Lu) peroxides have been …
processes. Rare-earth (group III and the lanthanides; Sc, Y, La–Lu) peroxides have been …
Oxidation of sulfur compounds by oxo-Re (V) complexes containing salophen ligands through radical pathway
H Il, I Gumus - Polyhedron, 2023 - Elsevier
Oxidation, which converts sulfides into sulfoxides, is a widely used method for producing
synthetic intermediates in various industries such as chemical, medicinal chemistry, and …
synthetic intermediates in various industries such as chemical, medicinal chemistry, and …
C═ N Bond Ozonolysis and β-Scission: A Breakthrough Approach to the Synthesis of ω-Functionalized Compounds from Carbonyl Derivatives
This work discloses a two-step, one-pot approach to ω-functionalized esters via cleavage of
the alicyclic fragment of cycloalkanone semicarbazones. This approach is based on a …
the alicyclic fragment of cycloalkanone semicarbazones. This approach is based on a …