Endogenous photosensitizers in human skin

EL Bastos, FH Quina, MS Baptista - Chemical Reviews, 2023 - ACS Publications
Endogenous photosensitizers play a critical role in both beneficial and harmful light-induced
transformations in biological systems. Understanding their mode of action is essential for …

Alkane functionalization: Recent advances

NR Conceição, KT Mahmudov, MFCG da Silva… - Coordination Chemistry …, 2025 - Elsevier
Despite the progress of alternative/renewable energy technologies (solar, wind,
hydroelectric, geothermal, nuclear, hydrogen, bio, tidal and wave), still the fossil raw …

Scalable electrochemical aerobic oxygenation of indoles to isatins without electron transfer mediators by merging with an oxygen reduction reaction

W Zhuang, J Zhang, C Ma, JS Wright, X Zhang… - Organic …, 2022 - ACS Publications
An approach to electrochemical oxygenation of indoles leading to isatins was developed by
merging with a complementary cathode oxygen reduction reaction. The features of this …

Chemoselective decarboxylative oxygenation of carboxylic acids to access ketones, aldehydes, and peroxides

R Guan, G Chen, EL Bennett, Z Huang, J Xiao - Organic Letters, 2023 - ACS Publications
Reported here is a photocatalytic strategy for the chemoselective decarboxylative
oxygenation of carboxylic acids using Ce (III) catalysts and O2 as the oxidant. By simply …

Creating, Preserving, and Directing Carboxylate Radicals in Ni-Catalyzed C(sp3)–H Acyloxylation of Ethers, Ketones, and Alkanes with Diacyl Peroxides

VA Vil', YA Barsegyan, L Kuhn, AO Terent'ev… - …, 2023 - ACS Publications
The reaction of Ni (II) acetate with diacyl peroxides produces high-valence Ni-species
capable of catalytic oxidative acyloxylation of C (sp3)–H bonds in ethers, ketones, and …

Synergism of primary and secondary interactions in a crystalline hydrogen peroxide complex with tin

AG Medvedev, PA Egorov, AA Mikhaylov… - Nature …, 2024 - nature.com
Despite the significance of H2O2-metal adducts in catalysis, materials science and
biotechnology, the nature of the interactions between H2O2 and metal cations remains …

Electrochemical Generation of Peroxy Radicals and Subsequent Peroxidation of 1, 3-Dicarbonyls in an Undivided Cell

OV Bityukov, KV Skokova, VA Vil', GI Nikishin… - Organic …, 2023 - ACS Publications
The generation of peroxy radicals from hydroperoxides with subsequent selective
peroxidation of 1, 3-dicarbonyls in an undivided electrochemical cell under constant current …

Peroxide-Selective Reduction of O2 at Redox-Inactive Rare-Earth(III) Triflates Generates an Ambiphilic Peroxide

MJ Lueckheide, MZ Ertem, MA Michon… - Journal of the …, 2022 - ACS Publications
Metal peroxides are key species involved in a range of critical biological and synthetic
processes. Rare-earth (group III and the lanthanides; Sc, Y, La–Lu) peroxides have been …

Oxidation of sulfur compounds by oxo-Re (V) complexes containing salophen ligands through radical pathway

H Il, I Gumus - Polyhedron, 2023 - Elsevier
Oxidation, which converts sulfides into sulfoxides, is a widely used method for producing
synthetic intermediates in various industries such as chemical, medicinal chemistry, and …

C═ N Bond Ozonolysis and β-Scission: A Breakthrough Approach to the Synthesis of ω-Functionalized Compounds from Carbonyl Derivatives

DI Fomenkov, RA Budekhin, PS Radulov… - Organic …, 2024 - ACS Publications
This work discloses a two-step, one-pot approach to ω-functionalized esters via cleavage of
the alicyclic fragment of cycloalkanone semicarbazones. This approach is based on a …