The synthesis of biaryls from benzyne intermediates offers an alternative strategy to
conventional metal-catalyzed cross-coupling approaches. The concept is as old as benzyne …

This review with 206 references covers the literature published until March 2004 on the
development and applications of new efficient catalyst systems for the Suzuki palladium …

A mechanistic and computational study on the reductive cleavage of C–OMe bonds
catalyzed by Ni (COD) 2/PCy3 with silanes as reducing agents is reported herein …

Arynes hold significance for the efficient fusion of (hetero) arenes with diverse substrates,
advancing the construction of complex molecular frameworks. Employing multiple …

Though often perceived as the simple metaphorical hybrid of synthetic inorganic and
organic chemistry, synthetic organometallic chemistry continues to vigorously differentiate …

First-row metal complexes often undergo undesirable one-electron redox processes during
two-electron steps of catalytic cycles. We report the amination of aryl chlorides and bromides …

Structurally, boronic acids are trivalent boron-containing organic compounds that possess
one alkyl substituent (ie, a C–B bond) and two hydroxyl groups to fill the remaining valences …

A palladium-catalyzed domino aminopalladation/CH functionalization sequence has been
developed, and provides access to functionalized phenanthridines and isoquinolines. The …

The construction and transformation of metal− carbon (M− C) bonds constitute the central
themes of organometallic chemistry. Most of the work in this field has focused on traditional …

General approaches for fluorination, trifluoromethylation, and trifluoromethylthiolation were
developed based on the electrophilic nature of arynes. In these reactions, the addition of …