Direct photocatalyzed hydrogen atom transfer (HAT) for aliphatic C–H bonds elaboration

L Capaldo, D Ravelli, M Fagnoni - Chemical Reviews, 2021 - ACS Publications
Direct photocatalyzed hydrogen atom transfer (d-HAT) can be considered a method of
choice for the elaboration of aliphatic C–H bonds. In this manifold, a photocatalyst (PCHAT) …

Photons or electrons? A critical comparison of electrochemistry and photoredox catalysis for organic synthesis

NES Tay, D Lehnherr, T Rovis - Chemical reviews, 2021 - ACS Publications
Redox processes are at the heart of synthetic methods that rely on either electrochemistry or
photoredox catalysis, but how do electrochemistry and photoredox catalysis compare? Both …

Copper-catalyzed radical relay in C (sp 3)–H functionalization

Z Zhang, P Chen, G Liu - Chemical Society Reviews, 2022 - pubs.rsc.org
Radical-involved transition metal (TM) catalysis has greatly enabled new reactivities in
recent decades. Copper-catalyzed radical relay offers enormous potential in C (sp3)–H …

Recent development of aryl diazonium chemistry for the derivatization of aromatic compounds

F Mo, D Qiu, L Zhang, J Wang - Chemical Reviews, 2021 - ACS Publications
Aryl diazonium salts are versatile building blocks in organic synthesis. In light of the ever-
increasing importance of aryl diazonium salts spanning most disciplines of the chemical …

Carbon–sulfur bond formation via photochemical strategies: An efficient method for the synthesis of sulfur-containing compounds

D Yang, Q Yan, E Zhu, J Lv, WM He - Chinese Chemical Letters, 2022 - Elsevier
The development of green and convenient methods for C–S bond formation has received
significant attention because C–S bond widely occurs in many important pharmaceutical …

Dirhodium tetracarboxylates as catalysts for selective intermolecular C–H functionalization

HML Davies, K Liao - Nature Reviews Chemistry, 2019 - nature.com
C–H functionalization has become widely recognized as an exciting new strategy for the
synthesis of complex molecular targets. Instead of relying on functional groups as the …

En route to intermolecular cross-dehydrogenative coupling reactions

CY Huang, H Kang, J Li, CJ Li - The Journal of Organic Chemistry, 2019 - ACS Publications
Cross-coupling reaction between two C–H bonds has become a fundamental strategy in
synthetic organic chemistry. With its increasing importance in green chemistry, atom …

Photochemical and electrochemical strategies towards benzylic C− H functionalization: a recent update

M Oliva, GA Coppola… - Advanced Synthesis …, 2021 - Wiley Online Library
Transition metal‐catalysed processes have been widely used for the functionalization of
inert C− H bonds. Strategies for the functionalization of the benzylic C− H position having a …

Chemical and biology of sulfur fluoride exchange (SuFEx) click chemistry for drug discovery

SW Lucas, RZ Qin, KP Rakesh, KSS Kumar, HL Qin - Bioorganic Chemistry, 2023 - Elsevier
Compounds containing an Ssingle bondF bond have garnered intense interest in the
chemical and biological literature. In particular, sulfonyl fluorides (RSO 2 F) are commonly …

Selective functionalization of benzylic C (sp3)–H bonds to synthesize complex molecules

Y Zhang, T Zhang, S Das - Chem, 2022 - cell.com
Functionalization of the benzylic C (sp 3)–H bond has become a compelling and robust tool
to speed up pre-clinical research for" lead discovery." Besides bring frequently utilizated to …