C–H functionalization has been emerging as a powerful method to establish carbon–carbon
and carbon–heteroatom bonds. Many efforts have been devoted to transition-metal …

Sulfoxonium ylides are carbene precursors and safer alternatives for highly reactive and
unstable diazo compounds, and they are used extensively in the field of CH activation. The …

Among sulfoximine derivatives containing a chiral sulfur center, benzothiadiazine‐1‐oxides
are important for applications in medicinal chemistry. Here, we report that the combination of …

Herein, we report an acid-controlled highly tunable selectivity of Rh (III)-catalyzed [4+ 2] and
[3+ 3] annulations of N-carboxamide indoles with iodonium ylides lead to form synthetically …

Iodonium ylides have attracted considerable attention due to their unique properties and
numerous applications as versatile and sustainable reagents in organic synthesis …

Presented herein is a condition-controlled selective synthesis of pyrazolonyl
spirodihydroquinolines or pyrazolonyl spiroindolines through formal [5+ 1] or [4+ 1] …

The past decade has witnessed tremendous developments in transition‐metal‐catalyzed C−
H bond activation and subsequent carbene migratory insertion reactions, thus assisting in …

Cyclopropanes are one of the most important strained rings existing in various
pharmaceutical products and secondary metabolites. They are also widely used in total …

We described an Rhodium (III)‐catalyzed divergent C− H bond functionalization of N‐aryl
amidines with iodonium ylides. Carbazolones and zwitterionic salts were diversely …

The metal-catalyzed successive activation and functionalization of arene/heteroarene is one
of the most fundamental transformations in organic synthesis and leads to privileged …