Knotting matters: orderly molecular entanglements

Z Ashbridge, SDP Fielden, DA Leigh, L Pirvu… - Chemical Society …, 2022 - pubs.rsc.org
Entangling strands in a well-ordered manner can produce useful effects, from shoelaces and
fishing nets to brown paper packages tied up with strings. At the nanoscale, non-crystalline …

Recent trends in organic cage synthesis: push towards water-soluble organic cages

D Chakraborty, PS Mukherjee - Chemical Communications, 2022 - pubs.rsc.org
Research on organic cages has blossomed over the past few years into a mature field of
study which can contribute to solving some of the challenging problems. In this review we …

Dynamic covalent synthesis

FBL Cougnon, AR Stefankiewicz, S Ulrich - Chemical Science, 2024 - pubs.rsc.org
Dynamic covalent synthesis aims to precisely control the assembly of simple building blocks
linked by reversible covalent bonds to generate a single, structurally complex product. In …

Molecular Cages Self‐Assembled by Imine Condensation in Water

Y Lei, Q Chen, P Liu, L Wang, H Wang, B Li… - Angewandte …, 2021 - Wiley Online Library
Self‐assembly by imine condensation in aqueous media is a formidable task because of the
labile nature of imines in the presence of water. Here, by taking advantage of multivalence …

Self‐Assembly of a Purely Covalent Cage with Homochirality by Imine Formation in Water

Y Chen, G Wu, B Chen, H Qu, T Jiao… - Angewandte Chemie …, 2021 - Wiley Online Library
Self‐assembly of host molecules in aqueous media via metal–ligand coordination is well
developed. However, the preparation of purely covalent counterparts in water has remained …

Self-Assembly via Condensation of Imine or Its N-Substituted Derivatives

Y Chen, H Tang, H Chen, H Li - Accounts of Chemical Research, 2023 - ACS Publications
Conspectus Compared to traditionally used irreversible chemical reactions, dynamic
covalent chemistry (DCC) including imine formation represents a more advanced technique …

Self-assembly of a highly emissive pure organic imine-based stack for electroluminescence and cell imaging

X Zheng, W Zhu, C Zhang, Y Zhang… - Journal of the …, 2019 - ACS Publications
We demonstrated that a purely organic stack, namely, TPE-3-stack, can be assembled in
high yield by using dynamic imine chemistry. TPE-3-stack emits strong fluorescence not only …

Diastereoselective amplification of a mechanically chiral [2] catenane

K Caprice, D Pál, C Besnard, B Galmés… - Journal of the …, 2021 - ACS Publications
Achiral [2] catenanes composed of rings with inequivalent sides may adopt chiral co-
conformations. Their stereochemistry depends on the relative orientation of the interlocked …

Distinctive features and challenges in catenane chemistry

HY Au-Yeung, Y Deng - Chemical Science, 2022 - pubs.rsc.org
From being an aesthetic molecular object to a building block for the construction of
molecular machines, catenanes and related mechanically interlocked molecules (MIMs) …

Expedient decagram-scale synthesis of robust organic cages that bind sulfate strongly and selectively in water

ÉM Foyle, RJ Goodwin, CJT Cox… - Journal of the …, 2024 - ACS Publications
Selective anion recognition remains a key challenge in supramolecular chemistry: only a
very small number of systems that can function in water are known, and these nearly always …