Trifluoromethanesulfonic Anhydride as a Low‐Cost and Versatile Trifluoromethylation Reagent

Y Ouyang, XH Xu, FL Qing - Angewandte Chemie International …, 2018 - Wiley Online Library
A large number of reagents have been developed for the synthesis of trifluoromethylated
compounds. However, an ongoing challenge in trifluoromethylation reaction is the use of …

Towards a practical and efficient copper-catalyzed trifluoromethylation of aryl halides

T Schareina, XF Wu, A Zapf, A Cotté, M Gotta… - Topics in Catalysis, 2012 - Springer
The first copper-catalyzed trifluoromethylation of aryl halides was developed that utilizes
inexpensive trifluoroacetates. Providing low concentrations of the most economically …

Room-temperature base-free copper-catalyzed trifluoromethylation of organotrifluoroborates to trifluoromethylarenes

Y Huang, X Fang, X Lin, H Li, W He, KW Huang… - Tetrahedron, 2012 - Elsevier
An efficient room temperature copper-catalyzed trifluoromethylation of
organotrifluoroborates under the base free condition using an electrophilic …

Acid-controlled photoreactions of aryl alkanoates: competition of transesterification, decarboxylation, Fries-rearrangement and/or transposition

T Mori, M Takamoto, T Wada, Y Inoue - … & Photobiological Sciences, 2003 - pubs.rsc.org
2, 4, 6-Trimethylphenyl (mesityl) cyclohexanecarboxylate 1c and related mesityl esters 1a, b
and d–f were photodecarboxylated upon irradiation at 254 nm in neutral solvents to give …

Selectivity in photolysis of benzyl acetate and benzyl hexanoate upon cyclodextrin complexation

S Annalakshmi, K Pitchumani - Journal of Photochemistry and Photobiology …, 2006 - Elsevier
Irradiation of benzyl acetate (1) and benzyl hexanoate (2) in methanol yields products from
both heterolytic and homolytic pathways. However, in presence of cyclodextrin, photolysis of …

Photochemistry of Aromatic Compounds

A Gilbert - Photochemistry: Volume 36, 2007 - books.google.com
During the year, a number of reviews have been published which provide an overview for a
variety of aspects of the photochemistry of aromatic compounds. Topics which have formed …

Temperature effects, arrhenius activation parameters and rate constants for the photochemical reactivity of cyano, boronato, trifluoromethyl and methoxy substituted …

C Gonzalez, J Pincock - Photochemistry and photobiology, 2006 - Wiley Online Library
Total rate constants of decay (kt) as a function of temperature from–45 to+ 65° c for the
compounds 1 and 2 in AN and TFE and 3 and 4 in AN have been determined by …

[PDF][PDF] Investigation of PEPPSI precatalysts for controlled polymerization of-conjugated polymers from cheap starting materials

BJ Groombridge - 2015 - qmro.qmul.ac.uk
Since the discovery of catalyst-transfer polymerization in 2004 there has been significant
research into expanding the scope from Kumada couplings of poly-thiophenes mediated by …

[PDF][PDF] Substituent Effects on Photodecarboxylation Reactions of Arylacetic Acids

MDEA Atwater - 2015 - dam-oclc.bac-lac.gc.ca
Table 1: Quantum yields of PDC for selected arylacetic acids…………………………. 29
Table 2: Quantum yields of PDC for substituted phenylacetic and mandelic acids……. 55 …