Molecular magnetism has travelled a long way from the pioneering studies on electron
exchange and double exchange or spin crossover and valence tautomerism in small …

This review is dedicated to the synthesis, properties and potential applications of Prussian
blue analogs and other cyanide-bridged coordination polymers that have been recently …

Large-sized coordination clusters have emerged as a new class of molecular materials in
which many metal atoms and organic ligands are integrated to synergize their properties. As …

Harnessing sunlight via photosensitizing molecules is key for novel optical applications and
solar-to-chemical energy conversion. Exploiting abundant metals such as iron is attractive …

Molecular materials possessing switchable magneto-optical properties are of great interest
due to their potential applications in spintronics and molecular devices. However, switching …

Prussian blue, Fe III 4 [Fe II (CN) 6] 3· nH 2 O (n= 14∼ 16), is one of the most classical mixed-
valence complexes and was used as pigments. Combinations of different metal ions lead to …

FeCo Prussian blue analogues of general formula A x Co y [Fe (CN) 6] z are responsive,
non-stoichiometric materials whose magnetic and optical properties can be reversibly …

The engineering of intermolecular interaction is challenging but critical for magnetically
switchable molecules. Here, we prepared two cyanide‐bridged [Fe4Co4] cube complexes …

A cyanide-bridged [Fe2Co2] molecular square complex,{[Fe (Tp)(CN) 3] 2 [Co (L) 2] 2}(BF4)
2· 2CH3CN· 6H2O [1; Tp= hydrotris (pyrazol-1-yl) borate and L= bis (1-ethyl-1 H-imidazol-2 …

Polynuclear coordination clusters (PCCs) provide considerable design capabilities towards
various functions based on structural non-rigidity and spin state transitions, optical …