Electrolyte Effects on CO2 Electrochemical Reduction to CO
Conspectus The electrochemical reduction of CO2 (CO2RR) constitutes an alternative to
fossil fuel-based technologies for the production of fuels and commodity chemicals. Yet the …
fossil fuel-based technologies for the production of fuels and commodity chemicals. Yet the …
Uniting biological and chemical strategies for selective CO2 reduction
HS Shafaat, JY Yang - Nature Catalysis, 2021 - nature.com
The electrochemical reduction of CO2 into useful fuels and chemical feedstocks offers great
promise for conversion to a carbon-neutral economy. However, challenges in product …
promise for conversion to a carbon-neutral economy. However, challenges in product …
Unified mechanistic understanding of CO2 reduction to CO on transition metal and single atom catalysts
CO is the simplest product from CO2 electroreduction (CO2R), but the identity and nature of
its rate-limiting step remain controversial. Here we investigate the activity of transition metals …
its rate-limiting step remain controversial. Here we investigate the activity of transition metals …
How Temperature Affects the Selectivity of the Electrochemical CO2 Reduction on Copper
Copper is a unique catalyst for the electrochemical CO2 reduction reaction (CO2RR) as it
can produce multi-carbon products, such as ethylene and propanol. As practical …
can produce multi-carbon products, such as ethylene and propanol. As practical …
In operando investigations of oscillatory water and carbonate effects in MEA-based CO2 electrolysis devices
Membrane electrode assembly (MEA) CO 2 electrolyzers are a promising approach toward
producing carbon-neutral chemicals; however, they often have stability issues related to …
producing carbon-neutral chemicals; however, they often have stability issues related to …
A Cation Concentration Gradient Approach to Tune the Selectivity and Activity of CO2 Electroreduction
The linear scaling relationship of the binding energies of different intermediates limits the
catalyst performance in CO2 electroreduction. Here we demonstrate a cation concentration …
catalyst performance in CO2 electroreduction. Here we demonstrate a cation concentration …
Theories for Electrolyte Effects in CO2 Electroreduction
Conspectus Electrochemical CO2 reduction (eCO2R) enables the conversion of waste CO2
to high-value fuels and commodity chemicals powered by renewable electricity, thereby …
to high-value fuels and commodity chemicals powered by renewable electricity, thereby …
Templating Bicarbonate in the Second Coordination Sphere Enhances Electrochemical CO2 Reduction Catalyzed by Iron Porphyrins
Bicarbonate-based electrolytes are ubiquitous in aqueous electrochemical CO2 reduction,
particularly in heterogenous catalysis, where they demonstrate improved catalytic …
particularly in heterogenous catalysis, where they demonstrate improved catalytic …
Improving the intrinsic activity of electrocatalysts for sustainable energy conversion: where are we and where can we go?
As we are in the midst of a climate crisis, there is an urgent need to transition to the
sustainable production of fuels and chemicals. A promising strategy towards this transition is …
sustainable production of fuels and chemicals. A promising strategy towards this transition is …
In situ electrochemical Raman spectroscopy and ab initio molecular dynamics study of interfacial water on a single-crystal surface
The dynamics and chemistry of interfacial water are essential components of electrocatalysis
because the decomposition and formation of water molecules could dictate the protonation …
because the decomposition and formation of water molecules could dictate the protonation …