Designing sites in heterogeneous catalysis: are we reaching selectivities competitive with those of homogeneous catalysts?

F Zaera - Chemical Reviews, 2022 - ACS Publications
A critical review of different prominent nanotechnologies adapted to catalysis is provided,
with focus on how they contribute to the improvement of selectivity in heterogeneous …

New horizon of nanoparticle and cluster catalysis with dendrimers

K Yamamoto, T Imaoka, M Tanabe, T Kambe - Chemical reviews, 2019 - ACS Publications
Among various approaches synthesizing metal nanoparticles and tiny clusters, a template
method using dendrimers has significant advantages over other chemical approaches with …

Pd nanoparticles and aminopolymers confined in hollow silica spheres as efficient and reusable heterogeneous catalysts for semihydrogenation of alkynes

Y Kuwahara, H Kango, H Yamashita - ACS Catalysis, 2019 - ACS Publications
A yolk–shell nanostructured composite composed of Pd nanoparticles (NPs) and
aminopolymers, poly (ethylenimine)(PEI), confined in hollow silica spheres which act as an …

Mesoporous silica stabilized MOF nanoreactor for highly selective semi-hydrogenation of phenylacetylene via synergistic effect of Pd and Ru single site

Z Li, M Hu, J Liu, W Wang, Y Li, W Fan, Y Gong, J Yao… - Nano Research, 2022 - Springer
Selective semi-hydrogenation of phenylacetylene to styrene is a crucial step in the
polystyrene industry. Although Pd-based catalysts are widely used in this reaction due to …

Mesoporous metal catalysts templated on clay nanotubes

A Glotov, A Stavitskaya, Y Chudakov… - Bulletin of the …, 2019 - academic.oup.com
Halloysite is a natural tubular aluminosilicate clay of ca. 50 nm diameter and 0.5–1.5
micrometers in length. The nanoarchitectural modification of halloysite inner/outer surfaces …

Magnetic polyaniline-chitosan nanocomposite decorated with palladium nanoparticles for enhanced catalytic reduction of 4-nitrophenol

MM Ayad, WA Amer, MG Kotp - Molecular Catalysis, 2017 - Elsevier
In this article, palladium (Pd) nanoparticles were deposited on a smart surface composed of
a synthetic polymer, a natural polymer and a magnetic inorganic material, polyaniline …

Efficient synthesis of monodisperse metal (Rh, Ru, Pd) nanoparticles supported on fibrous nanosilica (KCC-1) for catalysis

M Dhiman, B Chalke, V Polshettiwar - ACS Sustainable Chemistry …, 2015 - ACS Publications
We report a simple and sustainable protocol for the synthesis of monodisperse rhodium
(Rh), ruthenium (Ru), and palladium (Pd) metal nanoparticles supported on fibrous …

Tandem hydroformylation/hydrogenation over novel immobilized Rh-containing catalysts based on tertiary amine-functionalized hybrid inorganic-organic materials

D Gorbunov, M Nenasheva, E Naranov… - Applied Catalysis A …, 2021 - Elsevier
Non-phosphorous rhodium-containing catalysts for direct conversion of olefins to alcohols
via tandem hydroformylation/hydrogenation have been designed and synthesized …

One-step encapsulation of Pd nanoparticles in MOFs via a temperature control program

L Chen, X Chen, H Liu, C Bai, Y Li - Journal of Materials Chemistry A, 2015 - pubs.rsc.org
The control over the size and location of metal nanoparticles (MNPs) within metal–organic
frameworks (MOFs) is achieved in one step through a cooperative in situ metal precursor …

PdO nanoparticles enhancing the catalytic activity of Pd/carbon nanotubes for 4-nitrophenol reduction

C Wang, F Yang, W Yang, L Ren, Y Zhang, X Jia… - Rsc Advances, 2015 - pubs.rsc.org
In this work, we demonstrate that the presence of PdO nanoparticles can significantly
enhance the catalytic performance of Pd catalysts for the reduction of 4-nitrophenol (4-NP) …