Hydrogen atom storage upon Z-class borane ligand functions: an alternative approach to ligand cooperation
GR Owen - Chemical Society Reviews, 2012 - pubs.rsc.org
Ligand cooperation has become an important strategy in the development of new transition
metal based transformations. By using this approach some remarkable new catalytic …
metal based transformations. By using this approach some remarkable new catalytic …
Golden jubilee for scorpionates: Recent advances in organometallic chemistry and their role in catalysis
This review aims to describe some recent trends in organometallic complexes containing
scorpionate ligands. Particular attention will be paid to the ligands structure, reagents, and …
scorpionate ligands. Particular attention will be paid to the ligands structure, reagents, and …
Functional group migrations between boron and metal centres within transition metal–borane and–boryl complexes and cleavage of H–H, E–H and E–E′ bonds
GR Owen - Chemical Communications, 2016 - pubs.rsc.org
This feature article examines some of the recent advances in the chemistry of Z-type
transition metal–borane and X-type transition metal–boryl complexes. It focuses on the …
transition metal–borane and X-type transition metal–boryl complexes. It focuses on the …
Acyclic boron-containing π-ligand complexes: η 2-and η 3-coordination modes
DJH Emslie, BE Cowie, KB Kolpin - Dalton Transactions, 2012 - pubs.rsc.org
Cyclic boron-containing π-ligands such as boratabenzenes and borollides are well
established, in particular as supporting ligands. By contrast, the chemistry of acyclic boron …
established, in particular as supporting ligands. By contrast, the chemistry of acyclic boron …
Arene–ruthenium (ii) complexes containing inexpensive tris (dimethylamino) phosphine: highly efficient catalysts for the selective hydration of nitriles into amides
R García-Álvarez, J Díez, P Crochet… - Organometallics, 2011 - ACS Publications
The catalytic hydration of nitriles into amides, in water under neutral conditions, has been
studied using a series of arene–ruthenium (II) derivatives containing the commercially …
studied using a series of arene–ruthenium (II) derivatives containing the commercially …
Quantifying the Donor Strength of Ligand-Stabilized Main Group Fragments
Unusual binding properties, enabling the stabilization of elusive species, and beneficial
properties for homogeneous catalysts have been predicted and demonstrated for ligand …
properties for homogeneous catalysts have been predicted and demonstrated for ligand …
Sequential Migrations between Boron and Rhodium Centers: A Cooperative Process between Rhodium and a Monosubstituted Borohydride Unit
The sodium salt of a monosubstituted borohydride anion containing a 2-mercaptopyridyl unit
(mp) is reported herein. This compound was coordinated to a rhodium (I) center providing …
(mp) is reported herein. This compound was coordinated to a rhodium (I) center providing …
Scorpionate ligands based on 2-Mercaptopyridine: a ligand with a greater propensity to sting?
The synthesis and characterization of the first platinum group metal complexes of the
recently reported ligand [H2B (mp) 2]−(where mp= 2-mercaptopyridyl) are presented herein …
recently reported ligand [H2B (mp) 2]−(where mp= 2-mercaptopyridyl) are presented herein …
Strong agostic-type interactions in ruthenium benzylidene complexes containing 7-azaindole based scorpionate ligands
N Tsoureas, J Nunn, T Bevis, MF Haddow… - Dalton …, 2011 - pubs.rsc.org
The complexes [Ru (Tai) Cl {= C (H) Ph}(PCy3)](4) and [Ru (PhBai) Cl {= C (H)
Ph}(PCy3)](5)[where Tai= HB (7-azaindolyl) 3 and PhBai= Ph (H) B (7-azaindolyl) 2] have …
Ph}(PCy3)](5)[where Tai= HB (7-azaindolyl) 3 and PhBai= Ph (H) B (7-azaindolyl) 2] have …
STRUCTURE AND CATALYTIC PROPERTIES OF PALLADIUM(II) (ACETYLACETONATO- κ2O,O′)BIS(TRIS(DIETHYLAMINO)PHOSPHINE) …
MV Bykov, ZD Abramov, MV Pakhomova… - Journal of Structural …, 2022 - Springer
The structure of complex [Pd (acac){P (NEt2) 3} 2] BF4 (I) is determined by XRD. In the
crystal structure of I, the coordination sphere of palladium is characterized by a significantly …
crystal structure of I, the coordination sphere of palladium is characterized by a significantly …