Glycerol electro-oxidation at Pt in alkaline media: influence of mass transport and cations
Glycerol is an important biomass-derived product with potential to be applied on energy
converting systems or as platform molecule in electrosynthesis. In this work we studied the …
converting systems or as platform molecule in electrosynthesis. In this work we studied the …
[HTML][HTML] The role of coordinating anions in the supporting electrolyte during the electrocatalytic oxidation of glycerol on Pt electrodes
This research explores the glycerol electrooxidation reaction (GEOR) on a platinum
electrode, with a special emphasis on the role of the chemical properties of the anion …
electrode, with a special emphasis on the role of the chemical properties of the anion …
Electrocatalytic efficiency of the oxidation of small organic molecules under oscillatory regime
The electrocatalytic oxidation of small organic molecules is of general importance for energy-
related issues such as the fuel cells and electrochemical re-formation. The common …
related issues such as the fuel cells and electrochemical re-formation. The common …
Influence of anion adsorption on the parallel reaction pathways in the oscillatory electro-oxidation of methanol
We report the experimental study of the impact of anion adsorption on the two parallel
pathways of CO2 formation during the electro-oxidation of methanol on platinum. The effect …
pathways of CO2 formation during the electro-oxidation of methanol on platinum. The effect …
Long‐Lasting Oscillations in the Electro‐Oxidation of Formic Acid on PtSn Intermetallic Surfaces
Even when in contact with virtually infinite reservoirs, natural and manmade oscillators
typically drift in phase space on a time‐scale considerably slower than that of the intrinsic …
typically drift in phase space on a time‐scale considerably slower than that of the intrinsic …
The effect of temperature on the coupled slow and fast dynamics of an electrochemical oscillator
AA Zülke, H Varela - Scientific Reports, 2016 - nature.com
The coupling among disparate time-scales is ubiquitous in many chemical and biological
systems. We have recently investigated the effect of fast and, long-term, slow dynamics in …
systems. We have recently investigated the effect of fast and, long-term, slow dynamics in …
Production of volatile species during the oscillatory electro-oxidation of small organic molecules
MVF Delmonde, MA Nascimento… - The Journal of …, 2014 - ACS Publications
The study of complex reaction under oscillatory conditions has been proven to be useful in
uncovering features that are hidden under close to equilibrium regime. In particular, for the …
uncovering features that are hidden under close to equilibrium regime. In particular, for the …
Investigation of the oscillatory electrodissolution of the nickel–iron alloy
Among many chemical systems displaying oscillatory behavior, the anodic dissolution of
transition metals is considered one of the first, with the reports dating from as early as 1828 …
transition metals is considered one of the first, with the reports dating from as early as 1828 …
The electro-oxidation of ethylene glycol on platinum over a wide pH range: oscillations and temperature effects
We report a comprehensive study of the electro-oxidation of ethylene glycol (EG) on
platinum with emphasis on the effects exerted by the electrolyte pH, the EG concentration …
platinum with emphasis on the effects exerted by the electrolyte pH, the EG concentration …
Coupled slow and fast surface dynamics in an electrocatalytic oscillator: Model and simulations
MA Nascimento, R Nagao, M Eiswirth… - The Journal of Chemical …, 2014 - pubs.aip.org
The co-existence of disparate time scales is pervasive in many systems. In particular for
surface reactions, it has been shown that the long-term evolution of the core oscillator is …
surface reactions, it has been shown that the long-term evolution of the core oscillator is …