Pnictogen bonding in coordination chemistry
The pnictogen bond (PnB) is a noncovalent attraction between electrophilic pnictogen
atoms, originated from the anisotropic distribution of electron density on Pn in a molecular …
atoms, originated from the anisotropic distribution of electron density on Pn in a molecular …
Tunable σ-accepting, Z-type ligands for organometallic catalysis
Over the past decade, the chemistry of σ-accepting or Z-type ligands based on main group
elements has drawn renewed attention because of the realization that their interaction with a …
elements has drawn renewed attention because of the realization that their interaction with a …
Reversing Lewis acidity from bismuth to antimony
Investigations on the boundaries between the neutral and cationic models of (Mesityl) 2EX
(E= Sb, Bi and X= Cl−, OTf−) have facilitated reversing the Lewis acidity from bismuth to …
(E= Sb, Bi and X= Cl−, OTf−) have facilitated reversing the Lewis acidity from bismuth to …
The pnictogen bond forming ability of bonded bismuth atoms in molecular entities in the crystalline phase: A perspective
Thousands of crystal structures containing bismuth have been deposited in various crystal
structure databases since late last century; in many, a covalently or coordinately bonded …
structure databases since late last century; in many, a covalently or coordinately bonded …
Developments in the chemistry of stibine and bismuthine complexes
VK Greenacre, W Levason, G Reid - Coordination Chemistry Reviews, 2021 - Elsevier
New findings in the coordination chemistry of neutral stibine and bismuthine ligands are
reviewed. The article describes new ligand syntheses, coordination complexes of d-block …
reviewed. The article describes new ligand syntheses, coordination complexes of d-block …
Fundamental Study on Arsenic(III) Halides (AsX3; X = Br, I) toward the Construction of C3-Symmetrical Monodentate Arsenic Ligands
S Tanaka, M Konishi, H Imoto, Y Nakamura… - Inorganic …, 2020 - ACS Publications
Arsenic ligands have attracted considerable attention in coordination chemistry. Arsenic (III)
halides are the most important starting materials in the preparation of monodentate arsenic …
halides are the most important starting materials in the preparation of monodentate arsenic …
Bismuth species in the coordination sphere of transition metals: synthesis, bonding, coordination chemistry, and reactivity of molecular complexes
J Ramler, C Lichtenberg - Dalton Transactions, 2021 - pubs.rsc.org
This contribution is focused on bismuth species in the coordination sphere of transition
metals. In molecular transition metal complexes, three types of Bi–M bonding are …
metals. In molecular transition metal complexes, three types of Bi–M bonding are …
Highly Adaptive Nature of Group 15 Tris(quinolyl) Ligands─Studies with Coinage Metals
The substitution of heavier, more metallic atoms into classical organic ligand frameworks
provides an important strategy for tuning ligand properties, such as ligand bite and donor …
provides an important strategy for tuning ligand properties, such as ligand bite and donor …
Rare earth metal complexes supported by a tripodal tris (amido) ligand system featuring an arene anchor
A new tripodal tris (amido) ligand system featuring an arene anchor was developed and
applied to the coordination chemistry of rare earth metals. Two tris (amido) ligands with a 1 …
applied to the coordination chemistry of rare earth metals. Two tris (amido) ligands with a 1 …
Development of a novel scorpionate ligand with 6-methylpyridine and comparison of the structural and electronic properties of nickel (II) complexes with related tris …
Y Fujiwara, T Takayama, J Nakazawa… - Dalton …, 2022 - pubs.rsc.org
A novel anionic tridentate borate ligand with a 6-methylpyridyl donor, TpyMe, has been
synthesized. Comparison of the molecular structures and reactivities of nickel (II)-bromido …
synthesized. Comparison of the molecular structures and reactivities of nickel (II)-bromido …