Current challenges and routes forward for nonaqueous lithium–air batteries

T Liu, JP Vivek, EW Zhao, J Lei, N Garcia-Araez… - Chemical …, 2020 - ACS Publications
Nonaqueous lithium–air batteries have garnered considerable research interest over the
past decade due to their extremely high theoretical energy densities and potentially low cost …

Superoxide ion: generation and chemical implications

M Hayyan, MA Hashim, IM AlNashef - Chemical reviews, 2016 - ACS Publications
Superoxide ion (O2•–) is of great significance as a radical species implicated in diverse
chemical and biological systems. However, the chemistry knowledge of O2•–is rather …

Singlet oxygen generation as a major cause for parasitic reactions during cycling of aprotic lithium–oxygen batteries

N Mahne, B Schafzahl, C Leypold, M Leypold… - Nature Energy, 2017 - nature.com
Non-aqueous metal–oxygen batteries depend critically on the reversible formation/
decomposition of metal oxides on cycling. Irreversible parasitic reactions cause poor …

Solvating additives drive solution-mediated electrochemistry and enhance toroid growth in non-aqueous Li–O2 batteries

NB Aetukuri, BD McCloskey, JM García, LE Krupp… - Nature …, 2015 - nature.com
Given their high theoretical specific energy, lithium–oxygen batteries have received
enormous attention as possible alternatives to current state-of-the-art rechargeable Li–ion …

From lithium‐oxygen to lithium‐air batteries: challenges and opportunities

D Geng, N Ding, TSA Hor, SW Chien… - Advanced Energy …, 2016 - Wiley Online Library
Lithium‐air batteries have become a focus of research on future battery technologies.
Technical issues associated with lithium‐air batteries, however, are rather complex. Apart …

A general N-alkylation platform via copper metallaphotoredox and silyl radical activation of alkyl halides

NW Dow, A Cabré, DWC MacMillan - Chem, 2021 - cell.com
The catalytic union of amides, sulfonamides, anilines, imines, or N-heterocycles with a broad
spectrum of electronically and sterically diverse alkyl bromides has been achieved via a …

Quantitative analysis of superoxide ion and hydrogen peroxide produced from molecular oxygen on photoirradiated TiO2 particles

H Goto, Y Hanada, T Ohno, M Matsumura - Journal of Catalysis, 2004 - Elsevier
The reduction of molecular oxygen is the counter reaction of most photocatalytic reactions
proceeding oxidatively on titanium dioxide particles. We have quantitatively analyzed the …

The nature and mechanism of superoxide production by the electron transport chain: its relevance to aging

F Muller - Journal of the American Aging Association, 2000 - Springer
Most biogerontologists agree that oxygen (and nitrogen) free radicals play a major role in
the process of aging. The evidence strongly suggests that the electron transport chain …

Singlet Oxygen during Cycling of the Aprotic Sodium–O2 Battery

L Schafzahl, N Mahne, B Schafzahl… - Angewandte Chemie …, 2017 - Wiley Online Library
Aprotic sodium–O2 batteries require the reversible formation/dissolution of sodium
superoxide (NaO2) on cycling. Poor cycle life has been associated with parasitic chemistry …

The role of iodide in the formation of lithium hydroxide in lithium–oxygen batteries

M Tułodziecki, GM Leverick… - Energy & …, 2017 - pubs.rsc.org
Lithium iodide has been studied extensively as a redox-mediator to reduce the charging
overpotential of Li–oxygen (Li–O2) batteries. Ambiguities exist regarding the influence of …