Electrode materials in modern organic electrochemistry
DM Heard, AJJ Lennox - Angewandte Chemie International …, 2020 - Wiley Online Library
The choice of electrode material is critical for achieving optimal yields and selectivity in
synthetic organic electrochemistry. The material imparts significant influence on the kinetics …
synthetic organic electrochemistry. The material imparts significant influence on the kinetics …
Electrochemical strategies for C–H functionalization and C–N bond formation
MD Kärkäs - Chemical Society Reviews, 2018 - pubs.rsc.org
Conventional methods for carrying out carbon–hydrogen functionalization and carbon–
nitrogen bond formation are typically conducted at elevated temperatures, and rely on …
nitrogen bond formation are typically conducted at elevated temperatures, and rely on …
Electrocatalytic C–H Activation
N Sauermann, TH Meyer, Y Qiu, L Ackermann - Acs Catalysis, 2018 - ACS Publications
C–H activation has emerged as a transformative tool in molecular synthesis, but until
recently oxidative C–H activations have largely involved the use of stoichiometric amounts of …
recently oxidative C–H activations have largely involved the use of stoichiometric amounts of …
Chemoselective electrosynthesis using rapid alternating polarity
Y Kawamata, K Hayashi, E Carlson… - Journal of the …, 2021 - ACS Publications
Challenges in the selective manipulation of functional groups (chemoselectivity) in organic
synthesis have historically been overcome either by using reagents/catalysts that tunably …
synthesis have historically been overcome either by using reagents/catalysts that tunably …
Direct electrochemical defluorinative carboxylation of α-CF 3 alkenes with carbon dioxide
XT Gao, Z Zhang, X Wang, JS Tian, SL Xie, F Zhou… - Chemical …, 2020 - pubs.rsc.org
An unprecedented γ-carboxylation of α-CF3 alkenes with CO2 is reported. This approach
constitutes a rare example of using electrochemical methods to achieve regioselectivity …
constitutes a rare example of using electrochemical methods to achieve regioselectivity …
Green electrosynthesis of drug metabolites
In this concise review, the field of electrosynthesis (ES) as a green methodology for
understanding drug metabolites linked to toxicology is exemplified. ES describes the …
understanding drug metabolites linked to toxicology is exemplified. ES describes the …
Electrochemical behavior and voltammetric determination of two synthetic aroyl amides opioids
In the present work, we describe the electrochemical behaviour of two opioids structurally
related to aroyl amides of forensic interest, namely U-47700 and AH-7921. The data …
related to aroyl amides of forensic interest, namely U-47700 and AH-7921. The data …
Amino acids in electrochemical metal-free benzylic CH amidation
S Strekalova, A Kononov, Y Budnikova - Tetrahedron Letters, 2022 - Elsevier
This report describes the mild electrochemical metal-, oxidant-, additive-free site-selective
direct Csingle bond H amidation of benzyl C (sp 3)-H bonds in an undivided cell using α …
direct Csingle bond H amidation of benzyl C (sp 3)-H bonds in an undivided cell using α …
Electrochemical Scaled‐up Synthesis of Cyclic Enecarbamates as Starting Materials for Medicinal Chemistry Relevant Building Bocks
OD Tereshchenko, MY Perebiynis… - Advanced Synthesis …, 2020 - Wiley Online Library
The electrochemical Shono oxidation of Boc‐protected cyclic amines was revised. The
conditions for scalable electrochemical synthesis of cyclic enecarbamates were found. The …
conditions for scalable electrochemical synthesis of cyclic enecarbamates were found. The …
Metabolism mimicry: an electrosynthetic method for the selective deethylation of tertiary benzamides
The electrosynthetic deethylation of tertiary amides, commonly encountered moieties in
pharmaceuticals and agrochemicals, is an analogue of the function of cytochrome P450 …
pharmaceuticals and agrochemicals, is an analogue of the function of cytochrome P450 …