The use of transition metals to catalyse the addition of hydridoboranes to unsaturated
organic molecules was initially realised several decades ago. Although this area of …

Organoboron reagents represent a unique class of compounds because of their utility in
modern synthetic organic chemistry, often affording unprecedented reactivity. The …

Conspectus Transition metal catalyzed asymmetric hydrofunctionalization of readily
available unsaturated hydrocarbons presents one of the most straightforward and atom …

A Co-catalyzed highly regio-and enantioselective reductive coupling of alkynes and
aldehydes has been developed under visible light photoredox dual catalysis. A variety of …

This review highlights the hydroelementation reactions of conjugated and separated diynes,
which depending on the process conditions, catalytic system, as well as the type of reagents …

Selective defluoroborylation and asymmetric hydroboration reactions of fluoroalkyl-
substituted terminal alkenes with pinacolborane (HBpin) have been developed with cobalt …

Abstract Chromium‐catalyzed enantioselective Nozaki–Hiyama–Kishi (NHK) reaction
represents one of the most powerful approaches for the formation of chiral carbon …

During the past decade, many research groups have described catalytic methods for 1, 2‐
carboboration, allowing access to structurally complex organoboronates from alkenes …

Hydrofunctionalization of alkenes and alkynes is increasingly important in preparing and
modifying carbon-centered organic molecules such as pharmaceuticals, agrochemicals, and …

The structural diversity of sp3‐triorganometallic reagents enhances their potentiality in the
modular construction of molecular complexity in chemical synthesis. Despite significant …