12-MC-4 metallacrowns as versatile tools for SMM research

P Happ, C Plenk, E Rentschler - Coordination Chemistry Reviews, 2015 - Elsevier
The outstanding chemical and structural features of 12-MC-4 metallacrowns allow for
versatile applications in magneto-chemical research. Herein, we present three novel …

Adventures in the coordination chemistry of 2-pyridyl oximes: On the way to 3d/4f-metal coordination clusters

ZG Lada, CD Polyzou, V Nika, TC Stamatatos… - Inorganica Chimica …, 2022 - Elsevier
Molecular compounds containing both 3d-and 4f-metal ions have played an important role
in the development of inorganic chemistry in the last 15 years or so because of their …

Controllable formation of heterotrimetallic coordination compounds: systematically incorporating lanthanide and alkali metal ions into the manganese 12-metallacrown …

MR Azar, TT Boron III, JC Lutter, CI Daly… - Inorganic …, 2014 - ACS Publications
The inclusion of LnIII ions into the 12-MC-4 framework generates the first heterotrimetallic
complexes of this molecular class. The controllable and deliberate preparations of these …

Combining Azide, Carboxylate, and 2-Pyridyloximate Ligands in Transition-Metal Chemistry: Ferromagnetic NiII5 Clusters with a Bowtie Skeleton

C Papatriantafyllopoulou, TC Stamatatos… - Inorganic …, 2010 - ACS Publications
The combined use of the anion of phenyl (2-pyridyl) ketone oxime (ppko−) and azides (N3−)
in nickel (II) carboxylate chemistry has afforded two new NiII5 clusters,[Ni5 (O2CR′) 2 (N3) …

Antiferromagnetic versus Ferromagnetic Exchange Interactions in Bis(μ-Ooximate)dinickel(II) Units for a Series of Closely Related Cube Shaped Carboxamideoximate-Bridged …

MA Palacios, AJ Mota, JE Perea-Buceta… - Inorganic …, 2010 - ACS Publications
The syntheses, crystal structures, and the experimental and theoretical magnetochemical
characterization for three tetrametallic Ni (II) clusters, namely,[Ni4 (L) 4 (Cl) 2 (MeOH) …

A novel Cu (II) dimer containing oxime-hydrazone Schiff base ligands with an unusual mode of coordination: Study of magnetic, autoreduction and solution properties

M Sutradhar, TR Barman, J Klanke, MGB Drew… - Polyhedron, 2013 - Elsevier
Synthesis of a new hydrazone based Schiff base ligand, 3-methylpyrazole-5-
carbohydrazone of 2, 3-butanedione monoxime (HL) is reported. The reaction of Cu (ClO4) …

The sulfate ligand as a promising “player” in 3d-metal cluster chemistry

C Papatriantafyllopoulou, E Manessi-Zoupa… - Inorganica Chimica …, 2009 - Elsevier
The potentiality of the sulfate ligand in the chemistry of polynuclear 3d-metal complexes
(clusters) is illustrated through few, representative examples from our own research. A …

In search of molecules displaying ferromagnetic exchange: Multiple-decker Ni 12 and Ni 16 complexes from the use of pyridine-2-amidoxime

CG Efthymiou, L Cunha-Silva, SP Perlepes… - Dalton …, 2016 - pubs.rsc.org
The use of pyridine-2-amidoxime (pyaoxH2) in Ni chemistry has provided access to a
dodecanuclear complex and a hexadecanuclear Ni cluster, namely [Ni12 (pyaox) 6 …

Modeling the solvent extraction of cadmium (II) from aqueous chloride solutions by 2-pyridyl ketoximes: A coordination chemistry approach

EC Mazarakioti, AS Beobide, V Angelidou… - Molecules, 2019 - mdpi.com
The goal of this work is to model the nature of the chemical species [CdCl2 (extractant) 2]
that are formed during the solvent (or liquid-liquid) extraction of the toxic cadmium (II) from …

S-shaped decanuclear heterometallic [Ni 8 Ln 2] complexes [Ln (iii)= Gd, Tb, Dy and Ho]: theoretical modeling of the magnetic properties of the gadolinium analogue

S Hossain, S Das, A Chakraborty, F Lloret, J Cano… - Dalton …, 2014 - pubs.rsc.org
The reaction of 8-quinolinol-2-carboaldoxime (LH2) with NiII and LnIII salts afforded the
heterometallic decanuclear compounds [Ni8Dy2 (μ3-OH) 2 (L) 8 (LH) 2 (H2O) 6](ClO4) 2 …