Organic synthesis with the most abundant transition metal–iron: from rust to multitasking catalysts

S Rana, JP Biswas, S Paul, A Paik… - Chemical Society Reviews, 2021 - pubs.rsc.org
In industries and academic laboratories, several late transition metal-catalyzed prerequisite
reactions are widely performed during single and multistep synthesis. However, besides the …

Iron-catalyzed C–H bond activation

R Shang, L Ilies, E Nakamura - Chemical Reviews, 2017 - ACS Publications
Catalytic C–H bond activation, which was an elusive subject of chemical research until the
1990s, has now become a standard synthetic method for the formation of new C–C and C …

Mild metal-catalyzed C–H activation: examples and concepts

T Gensch, MN Hopkinson, F Glorius… - Chemical Society …, 2016 - pubs.rsc.org
Organic reactions that involve the direct functionalization of non-activated C–H bonds
represent an attractive class of transformations which maximize atom-and step-economy …

Iron catalysis in organic synthesis

I Bauer, HJ Knölker - Chemical reviews, 2015 - ACS Publications
The present review “Iron Catalysis in Organic Synthesis” covers the literature until the end of
June 2014 and represents a comprehensive update of a previous article published by Bolm …

Low-valent cobalt catalysis: new opportunities for C–H functionalization

K Gao, N Yoshikai - Accounts of Chemical Research, 2014 - ACS Publications
Rapid progress in the fields of organometallic chemistry and homogeneous catalysis has
made it possible for synthetic chemists to consider using ubiquitous yet unreactive C–H …

From C (sp 2)–H to C (sp 3)–H: systematic studies on transition metal-catalyzed oxidative C–C formation

BJ Li, ZJ Shi - Chemical Society Reviews, 2012 - pubs.rsc.org
In this tutorial review, we will summarize our recent efforts in transition metal-catalyzed
oxidative coupling via C–H functionalization of aromatic, benzylic and allylic C–H bonds …

Cobalt-catalyzed cyclization of aliphatic amides and terminal alkynes with silver-cocatalyst

J Zhang, H Chen, C Lin, Z Liu, C Wang… - Journal of the American …, 2015 - ACS Publications
A new method of cobalt-catalyzed synthesis of pyrrolidinones from aliphatic amides and
terminal alkynes was discovered through a C–H bond functionalization process on …

Iron-catalyzed/mediated oxidative transformation of C–H bonds

F Jia, Z Li - Organic Chemistry Frontiers, 2014 - pubs.rsc.org
It has been a long time since C–H bond oxidations first attracted chemists' attention. In the
last several decades, C–H bond oxidation has been extensively investigated and applied in …

Synthesis of Anthranilic Acid Derivatives through Iron-Catalyzed Ortho Amination of Aromatic Carboxamides with N-Chloroamines

T Matsubara, S Asako, L Ilies… - Journal of the American …, 2014 - ACS Publications
Arenes possessing an 8-quinolinylamide group as a directing group are ortho aminated with
N-chloroamines and N-benzoyloxyamines in the presence of an iron/diphosphine catalyst …

β-Arylation of Carboxamides Via Iron-Catalyzed C(sp3)–H Bond Activation

R Shang, R Shang - New Carbon–Carbon Coupling Reactions Based on …, 2017 - Springer
Abstract Directed C (sp 3)–H bond functionalization has been studied mainly by using
precious metal catalysts, such as Pd, Ru, Rh, and Ir under harsh conditions. Generally, these …