Click chemistry strategies for the accelerated synthesis of functional macromolecules

Z Geng, JJ Shin, Y Xi, CJ Hawker - Journal of Polymer Science, 2021 - Wiley Online Library
Click chemistry is one of the most powerful strategies for constructing polymeric soft
materials with precise control over architecture and functionality. In this review, we provide a …

Thiyl radicals in organic synthesis

F Denes, M Pichowicz, G Povie, P Renaud - Chemical reviews, 2014 - ACS Publications
Thiyl radicals have been used by nature in a broad range of biochemical processes. For
instance, thiol residues play an important role in many enzymatic processes as illustrated by …

50th Anniversary Perspective: Polymer Functionalization

E Blasco, MB Sims, AS Goldmann, BS Sumerlin… - …, 2017 - ACS Publications
The translation of small molecule chemistries into efficient methodologies for polymer
functionalization spans several decades, enabling critical advances in soft matter materials …

Click chemistry in materials science

W Xi, TF Scott, CJ Kloxin… - Advanced Functional …, 2014 - Wiley Online Library
Despite originating only a little more than a decade ago, click chemistry has become one of
the most powerful paradigms in materials science, synthesis, and modification. By …

Post-polymerization modification reactions of poly (glycidyl methacrylate) s

EM Muzammil, A Khan, MC Stuparu - RSC advances, 2017 - pubs.rsc.org
Post-polymerisation modification of poly (glycidyl methacrylate)(PGMA) through the
nucleophilic ring opening reactions of the pendent epoxide groups allows for the installation …

Post‐Functionalization of Polymers via Orthogonal Ligation Chemistry

AS Goldmann, M Glassner, AJ Inglis… - Chemistry of Organo …, 2014 - Wiley Online Library
This chapter highlights the current status of critically selected post‐functionalization
techniques of polymers via orthogonal ligation chemistry, reports the major characteristics of …

Thiol‐epoxy “click” chemistry: Application in preparation and postpolymerization modification of polymers

MC Stuparu, A Khan - Journal of Polymer Science Part A …, 2016 - Wiley Online Library
Base‐catalyzed reaction between a thiol and an epoxide group is a simple fusion process
that leads to the formation of a β‐hydroxythio‐ether linkage. This reaction is efficient, regio …

Metal‐free click chemistry reactions on surfaces

J Escorihuela, ATM Marcelis… - Advanced Materials …, 2015 - Wiley Online Library
In the last decade, interest in the functionalization of surfaces and materials has increased
dramatically. In this regard, click chemistry deserves a central focus because of its mild …

SuFEx on the surface: a flexible platform for postpolymerization modification of polymer brushes

J Yatvin, K Brooks, J Locklin - Angewandte Chemie, 2015 - Wiley Online Library
Polymer brushes present a unique architecture for tailoring surface functionalities due to
their distinctive physicochemical properties. However, the polymerization chemistries used …

Externally stimulated click reactions for macromolecular syntheses

MA Tasdelen, B Kiskan, Y Yagci - Progress in Polymer Science, 2016 - Elsevier
Over the last decade, click chemistry reactions, that are fast, simple to use, easy to purify,
versatile, regiospecific, and give high product yields have gained significant importance for …