Direct conversion of white phosphorus to versatile phosphorus transfer reagents via oxidative onioation

M Donath, K Schwedtmann, T Schneider… - Nature Chemistry, 2022 - nature.com
The main feedstock for the value-added phosphorus chemicals used in industry and
research is white phosphorus (P4), from which the key intermediate for forming P (III) …

Modifying carbon nitride through extreme phosphorus substitution

Q Wang, H Gou, L Zhu, HT Huang, A Biswas… - ACS Materials …, 2019 - ACS Publications
A glassy carbon phosphonitride material with bulk chemical composition roughly
approximating C3N3P was synthesized through a high-pressure, high-temperature process …

Mechanosynthesis of a Structurally Characterized, Well‐Defined Graphitic Phosphorus‐Linked Carbon Nitride (g‐PCN) with Water Splitting Activity

BG Fiss, G Douglas, M Ferguson… - Advanced Materials …, 2022 - Wiley Online Library
Graphitic phosphorus‐linked triazine networks (g‐PCNs) are an emergent class of carbon
nitride materials that have attracted attention for their potential role in developing metal‐free …

The Reactivity of Cyameluric Chloride C6N7Cl3 towards Phosphines and Phosphine Oxides

C Posern, U Böhme, E Kroke - Zeitschrift für anorganische und …, 2018 - Wiley Online Library
Organophosphines (R2PH) and phosphineoxides (R2OPH) show a very high reactivity
towards cyameluric chloride C6N7Cl3. For example, 2, 4, 6‐trisdiphenylphosphino‐tri‐s …

A solid, amorphous, lithiated carbon phosphonitride displaying lithium ion conductivity

AP Purdy, WA Maza, BL Chaloux, JP Yesinowski… - Journal of Solid State …, 2022 - Elsevier
Thermal runaway reactions resulting in catastrophic battery failure and combustion have
invigorated a search for non-flammable electrolytes. We report the synthesis of non …

Synthesis and characterization of a high-temperature polycyanophosphate resin

JL Dysart, BL Chaloux, MT Finn… - … , Sulfur, and Silicon …, 2024 - Taylor & Francis
A phosphorus-containing polymer with very high thermo-oxidative stability was synthesized
for the first time by addition of silver nitrate to tricyanophosphine (P (CN) 3). By optimizing …

[PDF][PDF] The structures of 1: 1 and 1: 2 adducts of phosphanetricarbonitrile with 1, 4-diazabicyclo [2.2. 2] octane

AP Purdy, RJ Butcher, CA Klug - Acta Crystallographica Section E …, 2021 - journals.iucr.org
In the structures of 1: 1 and 1: 2 adducts of phosphanetricarbonitrile (C3N3P) with 1, 4-
diazabicyclo [2.2. 2] octane (C6H12N2), the 1: 1 adduct crystallizes in the orthorhombic …

Mild solvothermal growth of robust carbon phosphonitride films

BL Chaloux, JM Shockley, KJ Wahl, S Tsoi… - Chemistry of …, 2018 - ACS Publications
Solvothermal growth of thin (1–2 μm thick), uniform films of carbon phosphonitride on fused
quartz substrates has been achieved by self-reaction of 1 m P (CN) 3 in diphenyl ether at …

Mechanochemical synthesis of structurally well-defined graphitic phosphorus-linked carbon nitride (g-PCN) with water splitting activity

B Fiss, G Douglas, M Ferguson, J Becerra, J Valdez… - 2022 - chemrxiv.org
Heteroatom-doped carbon nitride (CN) materials have shown much potential as metal-free
photocatalysts for water splitting. Graphitic phosphorus-linked triazine network (g-PCN) …

Preparation of graphitic C3N3P material

A Epshteyn, B Yonke, T Strobel, H Gou - US Patent 9,409,936, 2016 - Google Patents
A new graphitic material has the empirical formula C 3 N 3 P and comprises triazine rings
bound together by phosphorus atoms, and/or other 5-or 6-membered rings with various …