Hydrogen spillover as a promising strategy for boosting heterogeneous catalysis and hydrogen storage
M Li, W Yin, J Pan, Y Zhu, N Sun, X Zhang… - Chemical Engineering …, 2023 - Elsevier
Hydrogen spillover, a common active species migration phenomenon, has drawn
tremendous attention in the past few years. The spilled atomic hydrogen can not only …
tremendous attention in the past few years. The spilled atomic hydrogen can not only …
[HTML][HTML] Magic of hydrogen spillover: Understanding and application
The hydrogen spillover effect (HSPE) plays an important role in heterogeneous catalysis
and hydrogen storage as an interfacial phenomenon, which facilitates the improvement of …
and hydrogen storage as an interfacial phenomenon, which facilitates the improvement of …
Metal–support interactions in metal/oxide catalysts and oxide–metal interactions in oxide/metal inverse catalysts
Solid catalysts usually consist of multicomponents, within which interfacial interactions have
been recognized as a key factor affecting structures and catalytic performance. Metal …
been recognized as a key factor affecting structures and catalytic performance. Metal …
Asymmetric Sites on the ZnZrOx Catalyst for Promoting Formate Formation and Transformation in CO2 Hydrogenation
The role of formate species for CO2 hydrogenation is still under debate. Although formate
has been frequently observed and commonly proposed as the possible intermediate, there …
has been frequently observed and commonly proposed as the possible intermediate, there …
Overturning CO2 Hydrogenation Selectivity with High Activity via Reaction-Induced Strong Metal–Support Interactions
Encapsulation of metal nanoparticles by support-derived materials known as the classical
strong metal–support interaction (SMSI) often happens upon thermal treatment of supported …
strong metal–support interaction (SMSI) often happens upon thermal treatment of supported …
Interfacial compatibility critically controls Ru/TiO2 metal-support interaction modes in CO2 hydrogenation
Supports can widely affect or even dominate the catalytic activity, selectivity, and stability of
metal nanoparticles through various metal-support interactions (MSIs). However, underlying …
metal nanoparticles through various metal-support interactions (MSIs). However, underlying …
Generation of oxide surface patches promoting H-spillover in Ru/(TiOx)MnO catalysts enables CO2 reduction to CO
The migration of reducible metal oxides (for example, TiO2) to the surface of metal
nanoparticles can inhibit sintering but has a strong negative impact on the catalytic activity …
nanoparticles can inhibit sintering but has a strong negative impact on the catalytic activity …
Uncovering the reaction mechanism behind CoO as active phase for CO2 hydrogenation
Transforming carbon dioxide into valuable chemicals and fuels, is a promising tool for
environmental and industrial purposes. Here, we present catalysts comprising of cobalt …
environmental and industrial purposes. Here, we present catalysts comprising of cobalt …
Tuning the CO2 Hydrogenation Selectivity of Rhodium Single‐Atom Catalysts on Zirconium Dioxide with Alkali Ions
Tuning the coordination environments of metal single atoms (M1) in single‐atom catalysts
has shown large impacts on catalytic activity and stability but often barely on selectivity in …
has shown large impacts on catalytic activity and stability but often barely on selectivity in …
Hydrogen spillover-driven synthesis of high-entropy alloy nanoparticles as a robust catalyst for CO2 hydrogenation
K Mori, N Hashimoto, N Kamiuchi, H Yoshida… - Nature …, 2021 - nature.com
High-entropy alloys (HEAs) have been intensively pursued as potentially advanced
materials because of their exceptional properties. However, the facile fabrication of …
materials because of their exceptional properties. However, the facile fabrication of …