Hydrogen spillover as a promising strategy for boosting heterogeneous catalysis and hydrogen storage

M Li, W Yin, J Pan, Y Zhu, N Sun, X Zhang… - Chemical Engineering …, 2023 - Elsevier
Hydrogen spillover, a common active species migration phenomenon, has drawn
tremendous attention in the past few years. The spilled atomic hydrogen can not only …

[HTML][HTML] Magic of hydrogen spillover: Understanding and application

H Shen, H Li, Z Yang, C Li - Green Energy & Environment, 2022 - Elsevier
The hydrogen spillover effect (HSPE) plays an important role in heterogeneous catalysis
and hydrogen storage as an interfacial phenomenon, which facilitates the improvement of …

Metal–support interactions in metal/oxide catalysts and oxide–metal interactions in oxide/metal inverse catalysts

Y Li, Y Zhang, K Qian, W Huang - ACS Catalysis, 2022 - ACS Publications
Solid catalysts usually consist of multicomponents, within which interfacial interactions have
been recognized as a key factor affecting structures and catalytic performance. Metal …

Asymmetric Sites on the ZnZrOx Catalyst for Promoting Formate Formation and Transformation in CO2 Hydrogenation

Z Feng, C Tang, P Zhang, K Li, G Li… - Journal of the …, 2023 - ACS Publications
The role of formate species for CO2 hydrogenation is still under debate. Although formate
has been frequently observed and commonly proposed as the possible intermediate, there …

Overturning CO2 Hydrogenation Selectivity with High Activity via Reaction-Induced Strong Metal–Support Interactions

H Xin, L Lin, R Li, D Li, T Song, R Mu… - Journal of the …, 2022 - ACS Publications
Encapsulation of metal nanoparticles by support-derived materials known as the classical
strong metal–support interaction (SMSI) often happens upon thermal treatment of supported …

Interfacial compatibility critically controls Ru/TiO2 metal-support interaction modes in CO2 hydrogenation

J Zhou, Z Gao, G Xiang, T Zhai, Z Liu, W Zhao… - Nature …, 2022 - nature.com
Supports can widely affect or even dominate the catalytic activity, selectivity, and stability of
metal nanoparticles through various metal-support interactions (MSIs). However, underlying …

Generation of oxide surface patches promoting H-spillover in Ru/(TiOx)MnO catalysts enables CO2 reduction to CO

H Kang, L Zhu, S Li, S Yu, Y Niu, B Zhang, W Chu… - Nature Catalysis, 2023 - nature.com
The migration of reducible metal oxides (for example, TiO2) to the surface of metal
nanoparticles can inhibit sintering but has a strong negative impact on the catalytic activity …

Uncovering the reaction mechanism behind CoO as active phase for CO2 hydrogenation

IC Have, JJG Kromwijk, M Monai, D Ferri… - Nature …, 2022 - nature.com
Transforming carbon dioxide into valuable chemicals and fuels, is a promising tool for
environmental and industrial purposes. Here, we present catalysts comprising of cobalt …

Tuning the CO2 Hydrogenation Selectivity of Rhodium Single‐Atom Catalysts on Zirconium Dioxide with Alkali Ions

S Li, Y Xu, H Wang, B Teng, Q Liu, Q Li… - Angewandte Chemie …, 2023 - Wiley Online Library
Tuning the coordination environments of metal single atoms (M1) in single‐atom catalysts
has shown large impacts on catalytic activity and stability but often barely on selectivity in …

Hydrogen spillover-driven synthesis of high-entropy alloy nanoparticles as a robust catalyst for CO2 hydrogenation

K Mori, N Hashimoto, N Kamiuchi, H Yoshida… - Nature …, 2021 - nature.com
High-entropy alloys (HEAs) have been intensively pursued as potentially advanced
materials because of their exceptional properties. However, the facile fabrication of …