This Review compiles the evolution, mechanistic understanding, and more recent advances
in enantioselective Pd-catalyzed allylic substitution and decarboxylative and oxidative allylic …

Catalytic transformation of ubiquitous C–H bonds into valuable C–N bonds offers an efficient
synthetic approach to construct N-functionalized molecules. Over the last few decades …

Aliphatic allylic amines are found in a great variety of complex and biorelevant molecules.
The direct allylic C–H amination of alkenes serves as the most straightforward method …

Although they offer great potentials, the high reactivity and diverse pathways of radical
chemistry pose difficult problems for applications in organic synthesis. In addition to the …

Allylic amines are valuable synthetic targets en route to diverse biologically active amine
products. Current allylic C–H amination strategies remain limited with respect to the viable N …

Conspectus Asymmetric functionalization of inert C–H bonds is undoubtedly a synthetically
significant yet challenging bond-forming process, allowing for the preparation of densely …

In chemistry, a nucleophile is a molecule or ion with a lone pair of electrons. It donates both
bonding electrons to its reaction partner (the electrophile) when forming a chemical bond. 1 …

In this tutorial review, we will summarize our recent efforts in transition metal-catalyzed
oxidative coupling via C–H functionalization of aromatic, benzylic and allylic C–H bonds …

Oxidation reactions are key transformations in organic chemistry because they can increase
chemical complexity and incorporate heteroatom substituents into carbon-based molecules …

Transition‐metal‐catalyzed C H activation has recently emerged as a powerful tool for the
functionalization of organic molecules. While many efforts have focused on the …