Bioinspired Supercharging of Photoredox Catalysis for Applications in Energy and Chemical Manufacturing
Conspectus For more than a decade, photoredox catalysis has been demonstrating that
when photoactive catalysts are irradiated with visible light, reactions occur under milder …
when photoactive catalysts are irradiated with visible light, reactions occur under milder …
Cobalt (III) carbene complex with an electronic excited-state structure similar to cyclometalated iridium (III) compounds
Many organometallic iridium (III) complexes have photoactive excited states with mixed
metal-to-ligand and intraligand charge transfer (MLCT/ILCT) character, which form the basis …
metal-to-ligand and intraligand charge transfer (MLCT/ILCT) character, which form the basis …
Photoredox‐Catalyzed Decarboxylative Bromination, Chlorination and Thiocyanation Using Inorganic Salts
Decarboxylative halogenation reactions of alkyl carboxylic acids are highly valuable
reactions for the synthesis of structurally diverse alkyl halides. However, many reported …
reactions for the synthesis of structurally diverse alkyl halides. However, many reported …
High triplet energy iridium (III) isocyanoborato complex for photochemical upconversion, photoredox and energy transfer catalysis
L Schmid, F Glaser, R Schaer… - Journal of the American …, 2022 - ACS Publications
Cyclometalated Ir (III) complexes are often chosen as catalysts for challenging photoredox
and triplet–triplet-energy-transfer (TTET) catalyzed reactions, and they are of interest for …
and triplet–triplet-energy-transfer (TTET) catalyzed reactions, and they are of interest for …
The cost of quantum yield
JR Swierk - Organic Process Research & Development, 2023 - ACS Publications
The quantum yield (QY) of a photocatalytic reaction significantly influences its performance,
as reactions with low QYs require more intense light sources and longer illumination times to …
as reactions with low QYs require more intense light sources and longer illumination times to …
Radical redox annulations: a general light-driven method for the synthesis of saturated heterocycles
PRD Murray, INM Leibler, SM Hell, E Villalona… - ACS …, 2022 - ACS Publications
We introduce here a two-component annulation strategy that provides access to a diverse
collection of five-and six-membered saturated heterocycles from aryl alkenes and a family of …
collection of five-and six-membered saturated heterocycles from aryl alkenes and a family of …
Selenoviologen‐Appendant Metallacycles with Highly Stable Radical Cations and Long‐Lived Charge Separation States for Electrochromism and Photocatalysis
S Zhang, L Ma, W Ma, L Chen, K Gao… - Angewandte Chemie …, 2022 - Wiley Online Library
Two coordinated metallacycles (rhomboid for M1, hexagonal for M2) with selenoviologens
(SeV2+) pendants were synthesized via coordination‐driven hierarchical self‐assembly …
(SeV2+) pendants were synthesized via coordination‐driven hierarchical self‐assembly …
Understanding Ir (III) photocatalyst structure–activity relationships: a highly parallelized study of light-driven metal reduction processes
High-throughput synthesis and screening methods were used to measure the
photochemical activity of 1440 distinct heteroleptic [Ir (C^ N) 2 (N^ N)]+ complexes for the …
photochemical activity of 1440 distinct heteroleptic [Ir (C^ N) 2 (N^ N)]+ complexes for the …
Maximizing Photon-to-Electron Conversion for Atom Efficient Photoredox Catalysis
Photoredox catalysis is a powerful tool to access challenging and diverse syntheses.
Absorption of visible light forms the excited state catalyst (* PC) but photons may be wasted …
Absorption of visible light forms the excited state catalyst (* PC) but photons may be wasted …
Nanoscale and ultrafast in situ techniques to probe plasmon photocatalysis
Plasmonic photocatalysis uses the light-induced resonant oscillation of free electrons in a
metal nanoparticle to concentrate optical energy for driving chemical reactions. By altering …
metal nanoparticle to concentrate optical energy for driving chemical reactions. By altering …