Reactivity of metal clusters

Z Luo, AW Castleman Jr, SN Khanna - Chemical reviews, 2016 - ACS Publications
We summarize here the research advances on the reactivity of metal clusters. After a simple
introduction of apparatuses used for gas-phase cluster reactions, we focus on the reactivity …

Fluorescent metallic nanoclusters: electron dynamics, structure, and applications

P Yu, X Wen, YR Toh, X Ma… - Particle & Particle Systems …, 2015 - Wiley Online Library
Atomically precise Au nanoclusters (NCs) have emerged as fascinating fluorescent
nanomaterials and attracted considerable research interest in both fundamental research …

Intercluster Reactions between Au25(SR)18 and Ag44(SR)30

KR Krishnadas, A Ghosh, A Baksi… - Journal of the …, 2016 - ACS Publications
We present the first example of intercluster reactions between atomically precise, monolayer
protected noble metal clusters using Au25 (SR) 18 and Ag44 (SR) 30 (RS–= alkyl/aryl …

Electronic Origins of the Variable Efficiency of Room-Temperature Methane Activation by Homo- and Heteronuclear Cluster Oxide Cations [XYO2]+ (X, Y = Al, Si, Mg) …

J Li, S Zhou, J Zhang, M Schlangen… - Journal of the …, 2016 - ACS Publications
The reactivity of the homo-and heteronuclear oxide clusters [XYO2]+(X, Y= Al, Si, Mg) toward
methane was studied using Fourier transform ion cyclotron resonance mass spectrometry, in …

Vanadium cluster neutrals reacting with water: superatomic features and hydrogen evolution in a fishing mode

H Zhang, M Zhang, Y Jia, L Geng, B Yin… - The Journal of …, 2021 - ACS Publications
Hydrogen evolution reaction (HER) is known as the heart of various energy storage and
conversation systems of renewable energy sources. Here we observe the cluster reactions …

Advances in spectroscopy and dynamics of small and medium sized molecules and clusters

M Hochlaf - Physical Chemistry Chemical Physics, 2017 - pubs.rsc.org
Investigations of the spectroscopy and dynamics of small-and medium-sized molecules and
clusters represent a hot topic in atmospheric chemistry, biology, physics, atto-and femto …

Hydrogen release from a single water molecule on Vn+ (3 ≤ n ≤ 30)

H Zhang, H Wu, Y Jia, B Yin, L Geng, Z Luo… - Communications …, 2020 - nature.com
Water and its interactions with metals are closely bound up with human life, and the
reactivity of metal clusters with water is of fundamental importance for the understanding of …

Cyclotrimerization of Acetylene on Clusters Con+/Fen+/Nin+(n = 1–16)

W Gan, L Geng, B Yin, H Zhang, Z Luo… - The Journal of …, 2021 - ACS Publications
Cyclotrimerization of acetylene to benzene has attracted significant interest, but the role of
geometric and electronic effects on catalytic chemistry remains unclear. To fully elucidate the …

Advances in Naked Metal Clusters for Catalysis

Z Luo, A Shehzad - ChemPhysChem, 2024 - Wiley Online Library
The properties of sub–nano metal clusters are governed by quantum confinement and their
large surface–to–bulk ratios, atomically precise compositions and geometric/electronic …

Reactions of metal cluster anions with inorganic and organic molecules in the gas phase

YX Zhao, QY Liu, MQ Zhang, SG He - Dalton Transactions, 2016 - pubs.rsc.org
The study of gas phase ion–molecule reactions by state-of-the-art mass spectrometric
experiments in conjunction with quantum chemistry calculations offers an opportunity to …