Conspectus A decisive factor for obtaining high yields and selectivities in organic synthesis
is the choice of the proper solvent. Solvent selection is often guided by the intuitive …

While the influence of intramolecular electric fields is a known feature in enzymes, the use of
oriented external electric fields (EEF) to enhance or inhibit molecular reactivity is a …

Acid phosphatases (APases) are attractive enzymes for catalyzing large-scale industrial
phosphorylation reactions owing to their capacity of utilizing cheap phosphate donors as …

We describe the various escape channels available to dirhodium carbene intermediates
from cycloheptatrienyl diazo compounds located with density functional theory. An …

Quantum tunneling (QT) is not an effect often considered in chemistry, and rightfully so.
However, in many cases it is significant, and in some cases it is even considerable. In this …

The (2+ 2) and (4+ 2) cycloadditions are important approaches for the functional
derivatizations of nanocarbon and hexagonal boron nitride (hBN) materials. However, as …