The recent advances in the N‐heterocyclic carbene (NHC)‐organocatalyzed generation of
azolium enolate intermediates and their subsequent interception with electrophiles are …

Over the past decade, the catalysis of N-heterocyclic carbenes has achieved significant
advances. In this area, aldehydes, enals, and esters, are commonly employed as starting …

Amides are among the most fundamental functional groups and essential structural units,
widely used in chemistry, biochemistry and material science. Amide synthesis and …

The catalytic asymmetric synthesis of silicon-stereogenic organosilicon compounds has
been a long-standing challenging task and was recently accomplished through a handful of …

Axially chiral molecules have been widely used in inorganic, material and medicinal
chemistry. Compared with well-established N-heterocyclic carbene (NHC)-catalyzed …

Over the recent decades, due to the special electronic characteristics and diverse
reactivities, N‐heterocyclic carbene (NHC) has received significant interest in …

The activation of an ester by N-heterocyclic carbene (NHC) organocatalysis is an efficient
and important approach for generating an NHC-bound enolate intermediate, an important …

The use of functionalized aldimines has been demonstrated as newly structural 1, 4‐dipole
precursors under carbene catalysis. More importantly, enantiodivergent organocatalysis has …

In this study, the mechanism and origin of the stereoselectivity of an N-heterocyclic carbene
(NHC)-catalyzed transformation reaction between an enal and a β-silyl enone are …

Abstract An umpolung 1, 4‐addition of aryl iodides to enals promoted by cooperative (terpy)
Pd/NHC catalysis was developed that generates various bioactive β, β‐diaryl propanoate …