Water: A tale of two liquids

P Gallo, K Amann-Winkel, CA Angell… - Chemical …, 2016 - ACS Publications
Water is the most abundant liquid on earth and also the substance with the largest number
of anomalies in its properties. It is a prerequisite for life and as such a most important subject …

Advances in computational studies of the liquid–liquid transition in water and water-like models

JC Palmer, PH Poole, F Sciortino… - Chemical …, 2018 - ACS Publications
There has been uninterrupted interest in supercooled water ever since the pioneering
experiments of Speedy and Angell revealed sharp increases in this substance's response …

Perspective: Supercooled liquids and glasses

MD Ediger, P Harrowell - The Journal of chemical physics, 2012 - pubs.aip.org
Supercooled liquids and glasses are important for current and developing technologies.
Here we provide perspective on recent progress in this field. The interpretation of …

Liquids more stable than crystals in particles with limited valence and flexible bonds

F Smallenburg, F Sciortino - Nature Physics, 2013 - nature.com
All liquids (except helium owing to quantum effects) crystallize at low temperatures, forming
ordered structures. The competition between disorder, which stabilizes the liquid phase, and …

Widom line and dynamical crossovers as routes to understand supercritical water

P Gallo, D Corradini, M Rovere - Nature communications, 2014 - nature.com
Supercritical water is fundamental in many fields of applications and a precise
characterization of the supercritical state is of uttermost importance for this liquid. In a fluid …

The physics of empty liquids: From patchy particles to water

J Russo, F Leoni, F Martelli… - Reports on Progress in …, 2022 - iopscience.iop.org
Empty liquids represent a wide class of materials whose constituents arrange in a random
network through reversible bonds. Many key insights on the physical properties of empty …

Free energy surface of ST2 water near the liquid-liquid phase transition

PH Poole, RK Bowles, I Saika-Voivod… - The Journal of chemical …, 2013 - pubs.aip.org
We carry out umbrella sampling Monte Carlo simulations to evaluate the free energy surface
of the ST2 model of water as a function of two order parameters, the density and a bond …

Viscosity and self-diffusion of supercooled and stretched water from molecular dynamics simulations

P Montero de Hijes, E Sanz, L Joly… - The Journal of …, 2018 - pubs.aip.org
Among the numerous anomalies of water, the acceleration of dynamics under pressure is
particularly puzzling. Whereas the diffusivity anomaly observed in experiments has been …

Identifying time scales for violation/preservation of Stokes-Einstein relation in supercooled water

T Kawasaki, K Kim - Science Advances, 2017 - science.org
The violation of the Stokes-Einstein (SE) relation D~(η/T)− 1 between the shear viscosity η
and the translational diffusion constant D at temperature T is of great importance for …

Pressure dependence of viscosity in supercooled water and a unified approach for thermodynamic and dynamic anomalies of water

LP Singh, B Issenmann… - Proceedings of the …, 2017 - National Acad Sciences
The anomalous decrease of the viscosity of water with applied pressure has been known for
over a century. It occurs concurrently with major structural changes: The second …