Water: A tale of two liquids
Water is the most abundant liquid on earth and also the substance with the largest number
of anomalies in its properties. It is a prerequisite for life and as such a most important subject …
of anomalies in its properties. It is a prerequisite for life and as such a most important subject …
Advances in computational studies of the liquid–liquid transition in water and water-like models
There has been uninterrupted interest in supercooled water ever since the pioneering
experiments of Speedy and Angell revealed sharp increases in this substance's response …
experiments of Speedy and Angell revealed sharp increases in this substance's response …
Perspective: Supercooled liquids and glasses
MD Ediger, P Harrowell - The Journal of chemical physics, 2012 - pubs.aip.org
Supercooled liquids and glasses are important for current and developing technologies.
Here we provide perspective on recent progress in this field. The interpretation of …
Here we provide perspective on recent progress in this field. The interpretation of …
Liquids more stable than crystals in particles with limited valence and flexible bonds
F Smallenburg, F Sciortino - Nature Physics, 2013 - nature.com
All liquids (except helium owing to quantum effects) crystallize at low temperatures, forming
ordered structures. The competition between disorder, which stabilizes the liquid phase, and …
ordered structures. The competition between disorder, which stabilizes the liquid phase, and …
Widom line and dynamical crossovers as routes to understand supercritical water
Supercritical water is fundamental in many fields of applications and a precise
characterization of the supercritical state is of uttermost importance for this liquid. In a fluid …
characterization of the supercritical state is of uttermost importance for this liquid. In a fluid …
The physics of empty liquids: From patchy particles to water
Empty liquids represent a wide class of materials whose constituents arrange in a random
network through reversible bonds. Many key insights on the physical properties of empty …
network through reversible bonds. Many key insights on the physical properties of empty …
Free energy surface of ST2 water near the liquid-liquid phase transition
We carry out umbrella sampling Monte Carlo simulations to evaluate the free energy surface
of the ST2 model of water as a function of two order parameters, the density and a bond …
of the ST2 model of water as a function of two order parameters, the density and a bond …
Viscosity and self-diffusion of supercooled and stretched water from molecular dynamics simulations
Among the numerous anomalies of water, the acceleration of dynamics under pressure is
particularly puzzling. Whereas the diffusivity anomaly observed in experiments has been …
particularly puzzling. Whereas the diffusivity anomaly observed in experiments has been …
Identifying time scales for violation/preservation of Stokes-Einstein relation in supercooled water
T Kawasaki, K Kim - Science Advances, 2017 - science.org
The violation of the Stokes-Einstein (SE) relation D~(η/T)− 1 between the shear viscosity η
and the translational diffusion constant D at temperature T is of great importance for …
and the translational diffusion constant D at temperature T is of great importance for …
Pressure dependence of viscosity in supercooled water and a unified approach for thermodynamic and dynamic anomalies of water
LP Singh, B Issenmann… - Proceedings of the …, 2017 - National Acad Sciences
The anomalous decrease of the viscosity of water with applied pressure has been known for
over a century. It occurs concurrently with major structural changes: The second …
over a century. It occurs concurrently with major structural changes: The second …