[HTML][HTML] Rearrangements of organic peroxides and related processes

IA Yaremenko, VA Vil, DV Demchuk… - Beilstein journal of …, 2016 - beilstein-journals.org
This review is the first to collate and summarize main data on named and unnamed
rearrangement reactions of peroxides. It should be noted, that in the chemistry of peroxides …

Antiprotozoal and antitumor activity of natural polycyclic endoperoxides: Origin, structures and biological activity

VM Dembitsky, E Ermolenko, N Savidov, TA Gloriozova… - Molecules, 2021 - mdpi.com
Polycyclic endoperoxides are rare natural metabolites found and isolated in plants, fungi,
and marine invertebrates. The purpose of this review is a comparative analysis of the …

Inverse α-Effect as the Ariadne's Thread on the Way to Tricyclic Aminoperoxides: Avoiding Thermodynamic Traps in the Labyrinth of Possibilities

IA Yaremenko, YY Belyakova, PS Radulov… - Journal of the …, 2022 - ACS Publications
Stable tricyclic aminoperoxides can be selectively assembled via a catalyst-free three-
component condensation of β, δ′-triketones, H2O2, and an NH-group source such as …

Marriage of peroxides and nitrogen heterocycles: selective three-component assembly, peroxide-preserving rearrangement, and stereoelectronic source of unusual …

IA Yaremenko, YY Belyakova, PS Radulov… - Journal of the …, 2021 - ACS Publications
Stable bridged azaozonides can be selectively assembled via a catalyst-free three-
component condensation of 1, 5-diketones, hydrogen peroxide, and an NH-group source …

Synthesis of A-ring quinolones, nine-membered oxolactams and spiroindoles by oxidative transformations of 2, 3-indolotriterpenoids

EF Khusnutdinova, OB Kazakova, AN Lobov… - Organic & …, 2019 - pubs.rsc.org
This paper describes an access to new nitrogen-containing heterocyclic triterpenoids by the
reaction of 2, 3-indolotriterpenoids with ozone and dimethyldioxirane. The oxidation of …

Synthesis and anticancer activity of quinopimaric and maleopimaric acids' derivatives

EV Tretyakova, IE Smirnova, OB Kazakova… - Bioorganic & Medicinal …, 2014 - Elsevier
A series of quinopimaric and maleopimaric acids' derivatives modified in the E-ring, at the
carbonyl-and carboxyl-groups were synthesized and their in vitro cytotoxic activity was …

Triterpenoids with a five-membered A-ring: distribution in nature, transformations, synthesis, and biological activity

VV Grishko, IA Tolmacheva… - Chemistry of natural …, 2015 - Springer
The literature on the distribution in nature, structural variations, isolation, identification, and
biosynthesis issues of triterpenoids with a five-membered A-ring was reviewed. The …

Two-Component versus Three-Component Condensations in the Race between Hydrazide, Triketone, and Hydrogen Peroxide-How do All Six Reactive Centers …

IA Yaremenko, YY Belyakova, PS Radulov… - The Journal of …, 2023 - ACS Publications
Relief of stereoelectronic frustration drives the acid-catalyzed three-component
condensation of β, δ′-triketones with hydrazides and H2O2 to the direction where both …

Inhibition of alpha-glucosidase by synthetic derivatives of lupane, oleanane, ursane and dammarane triterpenoids

EF Khusnutdinova, IE Smirnova… - Natural Product …, 2016 - journals.sagepub.com
A variety of new and earlier synthesized lupane, oleanane, ursane and dammarane
triterpenoids have been investigated for their inhibitory activity against α-glucosidase. 2, 3 …

Diastereoselective synthesis of triterpenoid 1, 2, 4-trioxolanes by griesbaum co-ozonolysis

OB Kazakova, EF Khusnutdinova… - Journal of natural …, 2019 - ACS Publications
Diastereoselective synthesis of triterpenoid 1, 2, 4-trioxolanes by Griesbaum co-ozonolysis
was shown for the first time. Ozonolysis of 2-methoxyoximes (syn–anti-isomers mixture) of …