A comprehensive review on chemical properties and applications of biopolymers and their composites
In a world that canopies numerous opportunities to advance towards a green sustainable
life, biopolymer development offers a platform that fits into the paradigm of achieving an eco …
life, biopolymer development offers a platform that fits into the paradigm of achieving an eco …
Recent advances in metal‐mediated stereoselective ring‐opening polymerization of functional cyclic esters towards well‐defined poly (hydroxy acid) s: from …
H Li, RM Shakaroun, SM Guillaume… - … –A European Journal, 2020 - Wiley Online Library
Poly (hydroxy acid) s are a family of biocompatible and (bio) degradable polyesters with
various outcomes in different domains of application. To date, poly (hydroxy acid) s are best …
various outcomes in different domains of application. To date, poly (hydroxy acid) s are best …
Rare-earth complexes supported by tripodal tetradentate bis (phenolate) ligands: a privileged class of catalysts for ring-opening polymerization of cyclic esters
JF Carpentier - Organometallics, 2015 - ACS Publications
Tripodal dianionic diamino-or amino-alkoxy-bis (phenolate) ligands {ONXOR1, R2}(X= NR2,
OR) constitute a privileged class of ligands which has found much interest in combination …
OR) constitute a privileged class of ligands which has found much interest in combination …
Polymers from sugars: cyclic monomer synthesis, ring-opening polymerisation, material properties and applications
Plastics are ubiquitous in modern society. However, the reliance on fossil fuels and the
environmental persistence of most polymers make them unsustainable. Scientists are facing …
environmental persistence of most polymers make them unsustainable. Scientists are facing …
Renaissance of aliphatic polycarbonates: New techniques and biomedical applications
Aliphatic polycarbonates (APCs) were discovered a long time ago, with their conventional
applications mostly limited to low‐molecular‐weight oligomeric intermediates for …
applications mostly limited to low‐molecular‐weight oligomeric intermediates for …
Tacticity Control of Cyclic Poly (3‐Thiobutyrate) Prepared by Ring‐Opening Polymerization of Racemic β‐Thiobutyrolactone
H Li, J Ollivier, SM Guillaume… - Angewandte Chemie …, 2022 - Wiley Online Library
We report here on the ring‐opening polymerization (ROP) of racemic β‐thiobutyrolactone
(rac‐TBL), as the first chemical synthesis of poly (3‐thiobutyrolactone)(P3TB), the thioester …
(rac‐TBL), as the first chemical synthesis of poly (3‐thiobutyrolactone)(P3TB), the thioester …
Flame-retardant pressure-sensitive adhesives derived from epoxidized soybean oil and phosphorus-containing dicarboxylic acids
In this study, novel biobased pressure-sensitive adhesives (PSAs) derived from epoxidized
soybean oils and carboxylic acid-terminated polyesters were developed with flame …
soybean oils and carboxylic acid-terminated polyesters were developed with flame …
Discrete iron-based complexes: Applications in homogeneous coordination-insertion polymerization catalysis
Catalysis based on well-defined iron complexes has experienced a very strong growth over
the last decade, driven by the need to develop a chemistry that is increasingly in line with …
the last decade, driven by the need to develop a chemistry that is increasingly in line with …
Steric vs. electronic stereocontrol in syndio-or iso-selective ROP of functional chiral β-lactones mediated by achiral yttrium-bisphenolate complexes
R Ligny, MM Hänninen, SM Guillaume… - Chemical …, 2018 - pubs.rsc.org
Origins of stereoselectivity in ROP of racemic chiral cyclic esters promoted by achiral yttrium
complexes, resulting in the formation of highly heterotactic polylactide, and highly …
complexes, resulting in the formation of highly heterotactic polylactide, and highly …
Highly Syndiotactic or Isotactic Polyhydroxyalkanoates by Ligand‐Controlled Yttrium‐Catalyzed Stereoselective Ring‐Opening Polymerization of Functional Racemic …
R Ligny, MM Hänninen, SM Guillaume… - Angewandte …, 2017 - Wiley Online Library
Reported herein is the first stereoselective controlled ROP of a specific family of racemic
functional β‐lactones, namely 4‐alkoxymethylene‐β‐propiolactones (BPLORs). This …
functional β‐lactones, namely 4‐alkoxymethylene‐β‐propiolactones (BPLORs). This …