A comprehensive review on chemical properties and applications of biopolymers and their composites

A George, MR Sanjay, R Srisuk… - International journal of …, 2020 - Elsevier
In a world that canopies numerous opportunities to advance towards a green sustainable
life, biopolymer development offers a platform that fits into the paradigm of achieving an eco …

Recent advances in metal‐mediated stereoselective ring‐opening polymerization of functional cyclic esters towards well‐defined poly (hydroxy acid) s: from …

H Li, RM Shakaroun, SM Guillaume… - … –A European Journal, 2020 - Wiley Online Library
Poly (hydroxy acid) s are a family of biocompatible and (bio) degradable polyesters with
various outcomes in different domains of application. To date, poly (hydroxy acid) s are best …

Rare-earth complexes supported by tripodal tetradentate bis (phenolate) ligands: a privileged class of catalysts for ring-opening polymerization of cyclic esters

JF Carpentier - Organometallics, 2015 - ACS Publications
Tripodal dianionic diamino-or amino-alkoxy-bis (phenolate) ligands {ONXOR1, R2}(X= NR2,
OR) constitute a privileged class of ligands which has found much interest in combination …

Polymers from sugars: cyclic monomer synthesis, ring-opening polymerisation, material properties and applications

GL Gregory, EM López-Vidal, A Buchard - Chemical Communications, 2017 - pubs.rsc.org
Plastics are ubiquitous in modern society. However, the reliance on fossil fuels and the
environmental persistence of most polymers make them unsustainable. Scientists are facing …

Renaissance of aliphatic polycarbonates: New techniques and biomedical applications

J Xu, E Feng, J Song - Journal of Applied Polymer Science, 2014 - Wiley Online Library
Aliphatic polycarbonates (APCs) were discovered a long time ago, with their conventional
applications mostly limited to low‐molecular‐weight oligomeric intermediates for …

Tacticity Control of Cyclic Poly (3‐Thiobutyrate) Prepared by Ring‐Opening Polymerization of Racemic β‐Thiobutyrolactone

H Li, J Ollivier, SM Guillaume… - Angewandte Chemie …, 2022 - Wiley Online Library
We report here on the ring‐opening polymerization (ROP) of racemic β‐thiobutyrolactone
(rac‐TBL), as the first chemical synthesis of poly (3‐thiobutyrolactone)(P3TB), the thioester …

Flame-retardant pressure-sensitive adhesives derived from epoxidized soybean oil and phosphorus-containing dicarboxylic acids

XL Wang, L Chen, JN Wu, T Fu… - … Sustainable Chemistry & …, 2017 - ACS Publications
In this study, novel biobased pressure-sensitive adhesives (PSAs) derived from epoxidized
soybean oils and carboxylic acid-terminated polyesters were developed with flame …

Discrete iron-based complexes: Applications in homogeneous coordination-insertion polymerization catalysis

Y Champouret, OH Hashmi, M Visseaux - Coordination Chemistry Reviews, 2019 - Elsevier
Catalysis based on well-defined iron complexes has experienced a very strong growth over
the last decade, driven by the need to develop a chemistry that is increasingly in line with …

Steric vs. electronic stereocontrol in syndio-or iso-selective ROP of functional chiral β-lactones mediated by achiral yttrium-bisphenolate complexes

R Ligny, MM Hänninen, SM Guillaume… - Chemical …, 2018 - pubs.rsc.org
Origins of stereoselectivity in ROP of racemic chiral cyclic esters promoted by achiral yttrium
complexes, resulting in the formation of highly heterotactic polylactide, and highly …

Highly Syndiotactic or Isotactic Polyhydroxyalkanoates by Ligand‐Controlled Yttrium‐Catalyzed Stereoselective Ring‐Opening Polymerization of Functional Racemic …

R Ligny, MM Hänninen, SM Guillaume… - Angewandte …, 2017 - Wiley Online Library
Reported herein is the first stereoselective controlled ROP of a specific family of racemic
functional β‐lactones, namely 4‐alkoxymethylene‐β‐propiolactones (BPLORs). This …