Sustainability assessment of mechanochemistry by using the twelve principles of green chemistry

KJ Ardila‐Fierro, JG Hernández - ChemSusChem, 2021 - Wiley Online Library
In recent years, mechanochemistry has been growing into a widely accepted alternative for
chemical synthesis. In addition to their efficiency and practicality, mechanochemical …

Time‐resolved in situ monitoring of mechanochemical reactions

AAL Michalchuk, F Emmerling - … Chemie International Edition, 2022 - Wiley Online Library
Mechanochemical transformations offer environmentally benign synthesis routes, whilst
enhancing both the speed and selectivity of reactions. In this regard, mechanochemistry …

Tackling solubility issues in organic synthesis: solid-state cross-coupling of insoluble aryl halides

T Seo - Palladium-Catalyzed Mechanochemical Cross …, 2024 - Springer
Conventional organic synthesis generally relies on the use of liquid organic solvents to
dissolve the reactants. Therefore, reactions of sparingly soluble or insoluble substrates are …

Synthetic applications of oxidative aromatic coupling—from biphenols to nanographenes

M Grzybowski, B Sadowski… - Angewandte Chemie …, 2020 - Wiley Online Library
Oxidative aromatic coupling occupies a fundamental place in the modern chemistry of
aromatic compounds. It is a method of choice for the assembly of large and bewildering …

Helical Synthetic Nanographenes with Atomic Precision

Y Zhu, J Wang - Accounts of Chemical Research, 2023 - ACS Publications
Conspectus Understanding and harnessing the properties of nanoscale molecular entities
are considered as new frontiers in basic chemistry. In this regard, synthetic nanographene …

Scholl reaction as a powerful tool for the synthesis of nanographenes: a systematic review

RS Jassas, EU Mughal, A Sadiq, RI Alsantali… - RSC …, 2021 - pubs.rsc.org
Nanographenes, or extended polycyclic aromatic hydrocarbons, have been attracting
increasing attention owing to their widespread applications in organic electronics. However …

Methods for monitoring milling reactions and mechanistic studies of mechanochemistry: a primer

PA Julien, T Friščić - Crystal Growth & Design, 2022 - ACS Publications
Mechanochemistry by ball milling is garnering significant attention as an efficient and
versatile means of chemical synthesis which minimizes the need for solvents and reduces …

Raman spectroscopy for real-time and in situ monitoring of mechanochemical milling reactions

S Lukin, K Užarević, I Halasz - Nature Protocols, 2021 - nature.com
Solid-state milling has emerged as an alternative, sustainable approach for preparing
virtually all classes of compounds and materials. In situ reaction monitoring is essential to …

Tinkering with mechanochemical tools for scale up

JF Reynes, V Isoni, F García - … Chemie International Edition, 2023 - Wiley Online Library
Mechanochemistry provides an environmentally benign platform to develop more
sustainable chemical processes by limiting raw materials, energy use, and waste generation …

The Mechanochemical Synthesis and Activation of Carbon‐Rich π‐Conjugated Materials

M Xuan, C Schumacher, C Bolm, R Göstl… - Advanced …, 2022 - Wiley Online Library
Mechanochemistry uses mechanical force to break, form, and manipulate chemical bonds to
achieve functional transformations and syntheses. Over the last years, many innovative …