Periodic mesoporous organosilicas: from simple to complex bridges; a comprehensive overview of functions, morphologies and applications

P Van Der Voort, D Esquivel, E De Canck… - Chemical Society …, 2013 - pubs.rsc.org
Periodic Mesoporous Organosilicas (PMOs) were developed in 1999 and are basically
ordered templated mesoporous organosilicas, prepared by the combination of a surfactant …

Porous organic–inorganic hybrid materials for catalysis, energy and environmental applications

S Chongdar, S Bhattacharjee, P Bhanja… - Chemical …, 2022 - pubs.rsc.org
The introduction of organic functionalities into porous inorganic materials not only makes the
resulting hybrid porous framework to be more flexible and hydrophobic, but also provides …

Metal–organic frameworks as heterogeneous catalysts for oxidation reactions

A Dhakshinamoorthy, M Alvaro, H Garcia - Catalysis Science & …, 2011 - pubs.rsc.org
In this Perspective, we describe the use of metal–organic frameworks (MOFs) as
heterogeneous catalysts for oxidations using hydroperoxides or molecular oxygen. These …

Past, present, and future of periodic mesoporous organosilicas the PMOs

B Hatton, K Landskron, W Whitnall… - Accounts of chemical …, 2005 - ACS Publications
Periodic mesoporous organosilicas (PMOs) represent an exciting new class of organic−
inorganic nanocomposites targeted for a broad range of applications such as catalysis and …

Flexible and iridescent chiral nematic mesoporous organosilica films

KE Shopsowitz, WY Hamad… - Journal of the American …, 2012 - ACS Publications
Nanocrystalline cellulose (NCC) has been used to template ethylene-bridged mesoporous
organosilica films with long-range chirality and photonic properties. The structural color of …

Chiral metal–organic framework as a platform for cooperative catalysis in asymmetric cyanosilylation of aldehydes

C Zhu, Q Xia, X Chen, Y Liu, X Du, Y Cui - ACS Catalysis, 2016 - ACS Publications
In this work, we demonstrate cooperative asymmetric catalysis by a metal–organic
framework (MOF) as exemplified in the context of catalyzing cyanation of aldehydes with a …

Delineating similarities and dissimilarities in the use of metal organic frameworks and zeolites as heterogeneous catalysts for organic reactions

A Dhakshinamoorthy, M Alvaro, A Corma… - Dalton Transactions, 2011 - pubs.rsc.org
This perspective article is aimed at providing a comparison of similarities and dissimilarities
between the catalytic properties of zeolites and metal organic frameworks (MOFs). In the first …

Crossing the borders between homogeneous and heterogeneous catalysis: developing recoverable and reusable catalytic systems

A Corma, H Garcia - Topics in Catalysis, 2008 - Springer
Homogeneous and heterogeneous catalysis have developed independently as two
separate disciplines. Homogeneous catalysis is characterized by the use of highly active …

Supramolecular host‐guest systems in zeolites prepared by ship‐in‐a‐bottle synthesis

A Corma, H Garcia - European Journal of Inorganic Chemistry, 2004 - Wiley Online Library
Zeolites have a microporous system defining large cavities interconnected by smaller
windows. These cages can accommodate large molecules whose size, however, can be too …

Periodic mesoporous organosilica with large heterocyclic bridging groups

O Olkhovyk, M Jaroniec - Journal of the American Chemical …, 2005 - ACS Publications
Periodic mesoporous organosilica with a heterocyclic bridging group of large molecular
weight, tris [3-(trimethoxysilyl) propyl] isocyanurate, is reported. Incorporation of an organic …