Organophosphines have garnered attention from many avenues ranging from agriculture to
fine chemicals. One‐time use of phosphate resources has made sustainable use of …

Researchers around the globe have witnessed several breakthroughs in s-and p-block
metal chemistry. Over the past few years, several applications in catalysis associated with …

A thorough experimental examination of a series of half-sandwich Ru indenyl complexes
[Ru (η5-indenyl)(PPh2)(L)(PPh3)(L= PPh2H, CO, NCPh)] in the catalytic …

Catalytic hydrophosphination using [κ5-N, N, N, N, C-(Me3SiNCH2CH2)
2NCH2CH2NSiMe2CH2] Zr (1) under photolysis substantially enhances activity and avails …

The alkaline‐earth metals Mg and Ca are too inert for the direct metalation of primary and
secondary amines. Consequently, activation prior to use is required. Alternatively, the …

The synthesis, characterization, and catalytic application of six aluminum alkyl complexes
supported by various imino-phosphanamidinate chalcogenide ligands are described. Six …

Scientists have witnessed significant breakthroughs in s‐block metal chemistry. Over the
past few years, several applications in catalysis associated with alkaline‐earth metal …

A computational investigation of the intermolecular hydrophosphination of styrene and 2-
vinylpyridine, catalyzed by the heteroleptic β-diketiminato-stabilized calcium complex …

The treatment of 4, 5-dimethyl-1, 3-bis (2-pyridylmethyl)-1 H-imidazolium chloride with M [N
(SiMe3) 2] 2 (THF) 2 (M= Ca, Yb) in 1: 2 molar ratio results in the formation of a carbene …

A series of tri-coordinated zinc alkyl complexes with the general molecular formula [κ2NE-
{NHIRP (Ph)(E) N-Dipp} ZnEt][R= Dipp (2, 6-diisopropylphenyl), E= S (3a), Se (3b) and R …