Metal‐Catalyzed Hydrophosphination

BT Novas, R Waterman - ChemCatChem, 2022 - Wiley Online Library
Organophosphines have garnered attention from many avenues ranging from agriculture to
fine chemicals. One‐time use of phosphate resources has made sustainable use of …

Lanthanides and actinides: Annual survey of their organometallic chemistry covering the year 2019

JH Farnaby, T Chowdhury, SJ Horsewill… - Coordination Chemistry …, 2021 - Elsevier
This review summarizes the progress in organo-f-element chemistry during the year 2019.
Organo-f-element chemistry, including Sc, Y, the lanthanides and the actinides, has been a …

Stability and Solution Behavior of [(dpp-Bian)Ln] and [(dpp-Bian)LnX] (Ln = Yb, Tm, or Dy; X = I, F, or N3)

VA Dodonov, VM Makarov, MN Zemnyukova… - …, 2023 - ACS Publications
Treatment of an excess of ytterbium metal with dpp-Bian {dpp-Bian= 1, 2-bis [(2, 6-
diisopropylphenyl) imino] acenaphthene} in the presence of 0.5 equiv of iodine resulted in a …

Spectroscopic and electrochemical trends in divalent lanthanides through modulation of coordination environment

TC Jenks, ANW Kuda-Wedagedara, MD Bailey… - Inorganic …, 2020 - ACS Publications
Due to the importance of both visible-light luminescence and lanthanides in modern society,
the influence of the ligand environment on complexes of YbII were studied and compared …

Versatile Visible‐Light‐Driven Synthesis of Asymmetrical Phosphines and Phosphonium Salts

PB Arockiam, U Lennert, C Graf… - … A European Journal, 2020 - Wiley Online Library
Asymmetrically substituted tertiary phosphines and quaternary phosphonium salts are used
extensively in applications throughout industry and academia. Despite their significance …

Alkyl complexes of divalent lanthanides and heavy alkaline earth metals

DO Khristolyubov, DM Lyubov… - Russian Chemical …, 2021 - iopscience.iop.org
The review presents data on the synthesis, structure, reactivity, and catalytic activity of alkyl
derivatives of rare earth metals in the oxidation state+ 2 (Sm, Eu, Yb) and their analogues …

N-Heterocyclic Carbene-Coordinated M(II) (M = Yb, Sm, Ca) Bisamides: Expanding the Limits of Intermolecular Alkene Hydrophosphination

IV Lapshin, AV Cherkasov, KA Lyssenko… - Inorganic …, 2022 - ACS Publications
A series of NHC-stabilized amido compounds (NHC) n M [N (SiMe3) 2] 2 (M= Yb (II), Sm (II),
Ca (II); n= 1, 2) showed remarkable catalytic efficiency in addition of PhPH2 and PH3 to …

Ln (II) and Ca (II) NC sp3 N pincer type diarylmethanido complexes–promising catalysts for C–C and C–E (E= Si, P, N, S) bond formation

DO Khristolyubov, DM Lyubov, AS Shavyrin… - Inorganic Chemistry …, 2020 - pubs.rsc.org
Ln (II)(Ln= Yb, Sm) and Ca (II)[NCsp3N] pincer type diarylmethanido complexes [2, 2′-(4-
MeC6H3NMe2) 2CH] 2M (M= Yb (2), Sm (3), Ca (4)) coordinated by a tridentate …

Reversible hydrosilane addition to pyridines enabled by low-coordinate Ca (ii) and Yb (ii) hydrides

AN Selikhov, MA Bogachev, YV Nelyubina… - Inorganic Chemistry …, 2024 - pubs.rsc.org
The reactions of amides [tBu2CarbAr2] MN (SiMe3) 2 (THF)(M= Ca (5), Yb (6)) and
[tBu2CarbAr2] MN (SiMe3) 2 (M= Ca (7), Yb (8)) coordinated by a bulky carbazolyl ligand …

Recent advances in the carbon–phosphorus (C–P) bond formation from unsaturated compounds by s-and p-block metals

I Banerjee, TK Panda - Organic & Biomolecular Chemistry, 2021 - pubs.rsc.org
Researchers around the globe have witnessed several breakthroughs in s-and p-block
metal chemistry. Over the past few years, several applications in catalysis associated with …