Visible-to-NIR-light activated release: from small molecules to nanomaterials

R Weinstain, T Slanina, D Kand, P Klan - Chemical reviews, 2020 - ACS Publications
Photoactivatable (alternatively, photoremovable, photoreleasable, or photocleavable)
protecting groups (PPGs), also known as caged or photocaged compounds, are used to …

Family of BODIPY photocages cleaved by single photons of visible/near-infrared light

JA Peterson, C Wijesooriya, EJ Gehrmann… - Journal of the …, 2018 - ACS Publications
Photocages are light-sensitive chemical protecting groups that provide external control over
when, where, and how much of a biological substrate is activated in cells using targeted light …

Efficient far-red/near-IR absorbing BODIPY photocages by blocking unproductive conical intersections

P Shrestha, KC Dissanayake… - Journal of the …, 2020 - ACS Publications
Photocages are light-sensitive chemical protecting groups that give investigators control
over activation of biomolecules using targeted light irradiation. A compelling application of …

A general strategy for visible-light decaging based on the quinone trimethyl lock

DP Walton, DA Dougherty - Journal of the American Chemical …, 2017 - ACS Publications
Visible-light triggered quinone trimethyl locks are reported as a general design for long-
wavelength photoremovable protecting groups for alcohols and amines. Intramolecular …

Switchable synthesis of tritylone alcohols and 2-benzoylbenzoate esters from spiroindane-1, 3-diones

JY Kuan, JH Chen, JL Han - The Journal of Organic Chemistry, 2024 - ACS Publications
A solvent-controlled regioselective rearrangement reaction of spiroindane-1, 3-diones with a
leaving group has been developed. In acetonitrile solvent, the spiroindane-1, 3-diones 3 …

Phototriggered active alkyne generation from cyclopropenones with visible light-responsive photocatalysts

K Mishiro, T Kimura, T Furuyama, M Kunishima - Organic letters, 2019 - ACS Publications
A photocatalytic active alkyne generation reaction was developed using cyclopropenone as
a starting reagent. Visible light-responsive photocatalysts induced cyclopropenone …

Photoreleasable Protecting Groups Triggered by Sequential Two-Photon Absorption of Visible Light: Release of Carboxylic Acids from a Linked Anthraquinone-N …

MD Thum, DE Falvey - The Journal of Physical Chemistry A, 2018 - ACS Publications
A photoreleasable protecting group activated by sequential absorption of two visible
photons is designed, synthesized, and tested. Specifically, an anthraquinone-based …

Tweezer Dyads for H‐Bond Assisted Cooperativity in Tandem Uncaging Systems

M Klausen, V Dubois, S Picard… - … A European Journal, 2024 - Wiley Online Library
Abstract “Tandem” uncaging systems, in which a photolabile protecting group (PPG) is
sensitized by an energy‐harvesting antenna, may increase the photosensitivity of PPGs by …

Synthesis of tritylones via cascade reaction of arynes with 5-ethoxyoxazoles

P Garg, GC Upreti, A Singh - The Journal of Organic Chemistry, 2022 - ACS Publications
A cascade reaction involving arynes and 5-ethoxyoxazoles has been developed toward the
synthesis of 9-alkyl/aryl tritylones. 5-Ethoxyoxazoles undergo a [4+ 2] cycloaddition reaction …

Photodeprotection Reaction Mechanisms of Caged Species Utilizing a Photochromism Function

Y Guo, M Dai, DL Phillips, W Xu… - The Journal of Physical …, 2022 - ACS Publications
Acetoxy-1, 2, 2-tri (aryl) ethanone (1) is a novel and visual release-and-report system that
contains the photochromic diarylethylene function attached to the photocage …