Design and properties of supramolecular polymer gels

A Noro, M Hayashi, Y Matsushita - Soft Matter, 2012 - pubs.rsc.org
Supramolecular polymer gels are precisely designed physical gels brought together by
reversible secondary interactions to form three dimensional networks of melt …

Phase separation of supramolecular and dynamic block copolymers

MC Stuparu, A Khan, CJ Hawker - Polymer Chemistry, 2012 - pubs.rsc.org
The growing synergy between supramolecular chemistry and polymer synthesis is driven by
the realization that the dynamic nature of non-covalent interactions may bring new …

Supramolecular polylactides by the cooperative interaction of the end groups and stereocomplexation

M Brzezinski, T Biela - Macromolecules, 2015 - ACS Publications
The controlled ring-opening polymerization of l-lactide and d-lactide using 2-aminopyridine
(AP), isocytosine (IC), uridine (U), and 2-ureido-4 [1H]-pyrimidinone (UPy-OH) initiators with …

Promoted stereocomplex crystallization in supramolecular stereoblock copolymers of enantiomeric poly (lactic acid) s

J Bao, R Chang, G Shan, Y Bao, P Pan - Crystal Growth & Design, 2016 - ACS Publications
Telechelic and 3-arm star-shaped poly (l-lactic acid) s (PLLAs) and poly (d-lactic acid) s
(PDLAs) end-functionalized by 2-ureido-4 [1 H]-pyrimidione (UPy) self-complementary …

Temperature-activated nucleic acid nanostructures

K Zhang, X Zhu, F Jia, E Auyeung… - Journal of the American …, 2013 - ACS Publications
DNA and poly (N-isopropylacrylamide) are co-assembled onto gold nanoparticles. The DNA
sequences can be reversibly exposed or hidden from the polymer surface in response to …

Routes to Hydrogen Bonding Chain‐End Functionalized Polymers

A Bertrand, F Lortie, J Bernard - Macromolecular rapid …, 2012 - Wiley Online Library
The contribution of supramolecular chemistry to polymer science opens new perspectives
for the design of polymer materials exhibiting valuable properties and easier processability …

Synthesis, self‐assembly and reversible healing of supramolecular perfluoropolyethers

G Li, JJ Wie, NA Nguyen, WJ Chung… - Journal of Polymer …, 2013 - Wiley Online Library
The synthesis and thermomechanical properties of a novel class of self‐healing
perfluoropolyethers (PFPEs) is reported. By decoration of 2‐ureido‐4 [1H]‐pyrimidone end …

Self-complementary quadruple hydrogen bonding motifs: from design to function

PK Baruah, S Khan - RSC advances, 2013 - pubs.rsc.org
Self-assembly is an important phenomenon that allows nature to carry out many important
functions. Of the several non-covalent interactions present H-bonding finds a special place …

Entropy‐Driven Selectivity for Chain Scission: Where Macromolecules Cleave

K Pahnke, J Brandt, G Gryn'Ova, CY Lin… - Angewandte Chemie …, 2016 - Wiley Online Library
We show that, all other conditions being equal, bond cleavage in the middle of molecules is
entropically much more favored than bond cleavage at the end. Multiple experimental and …

Synthesis and Characterization of Ureidopyrimidone Telechelics by CuAAC “Click” Reaction: Effect of Tg and Polarity

S Bobade, Y Wang, J Mays, D Baskaran - Macromolecules, 2014 - ACS Publications
Telechelic oligomers functionalized with 2-ureido-4 [1 H]-pyrimidone (UPy), a quadruple
hydrogen bonding group, have been synthesized using a combination of atom-transfer …