Silicon quantum dots: surface matters

K Dohnalová, T Gregorkiewicz… - Journal of Physics …, 2014 - iopscience.iop.org
Silicon quantum dots (SiQDs) hold great promise for many future technologies. Silicon is
already at the core of photovoltaics and microelectronics, and SiQDs are capable of efficient …

Silicon nanocrystals: fundamental theory and implications for stimulated emission

VA Belyakov, VA Burdov, R Lockwood… - Advances in Optical …, 2008 - Wiley Online Library
Silicon nanocrystals (NCs) represent one of the most promising material systems for light
emission applications in microphotonics. In recent years, several groups have reported on …

Codoping n-and p-type impurities in colloidal silicon nanocrystals: Controlling luminescence energy from below bulk band gap to visible range

H Sugimoto, M Fujii, K Imakita, S Hayashi… - The Journal of …, 2013 - ACS Publications
We present a novel synthesis of ligand-free colloidal silicon nanocrystals (Si-NCs) that
exhibits efficient photoluminescence (PL) in a wide energy range (0.85–1.8 eV) overcoming …

All-inorganic near-infrared luminescent colloidal silicon nanocrystals: high dispersibility in polar liquid by phosphorus and boron codoping

H Sugimoto, M Fujii, K Imakita, S Hayashi… - The Journal of …, 2012 - ACS Publications
We demonstrate the formation of a new type of surfactant-free colloidal silicon nanocrystal
(Si-NC). The characteristic structural feature of the Si-NCs is simultaneous doping of …

All-inorganic colloidal silicon nanocrystals—surface modification by boron and phosphorus co-doping

M Fujii, H Sugimoto, K Imakita - Nanotechnology, 2016 - iopscience.iop.org
Abstract Si nanocrystals (Si-NCs) with extremely heavily B-and P-doped shells are
developed and their structural and optical properties are studied. Unlike conventional Si …

Size-dependence of acceptor and donor levels of boron and phosphorus codoped colloidal silicon nanocrystals

Y Hori, S Kano, H Sugimoto, K Imakita, M Fujii - Nano Letters, 2016 - ACS Publications
Size dependence of the boron (B) acceptor and phosphorus (P) donor levels of silicon (Si)
nanocrystals (NCs) measured from the vacuum level was obtained in a very wide size range …

Preferential positioning of dopants and co-dopants in embedded and freestanding Si nanocrystals

R Guerra, S Ossicini - Journal of the American Chemical Society, 2014 - ACS Publications
In this work we aim at understanding the effect of n-and p-type substitutional doping in the
case of matrix-embedded and freestanding Si nanocrystals. By means of ab initio …

Tight-Binding Calculations of the Optical Response of Optimally P-Doped Si Nanocrystals:<? format?> A Model for Localized Surface Plasmon Resonance

X Pi, C Delerue - Physical review letters, 2013 - APS
We present tight-binding calculations in the random-phase approximation of the optical
response of Silicon nanocrystals (Si NCs) ideally doped with large concentrations of …

Phosphorus and boron codoped colloidal silicon nanocrystals with inorganic atomic ligands

H Sugimoto, M Fujii, K Imakita, S Hayashi… - The Journal of …, 2013 - ACS Publications
The surface structure of P and B codoped colloidal Si-NCs are studied by
photoluminescence (PL) in hydrofluoric acid (HF) solution and X-ray photoelectron …

First-principles study of 2.2 nm silicon nanocrystals doped with boron

X Pi, X Chen, D Yang - The Journal of Physical Chemistry C, 2011 - ACS Publications
First-principles study of boron (B)-doped silicon nanocrystals (Si NCs) at 0 K in the
framework of density functional theory has been carried out. It is found that B prefers residing …