Accelerated reaction kinetics in microdroplets: Overview and recent developments

Z Wei, Y Li, RG Cooks, X Yan - Annual Review of Physical …, 2020 - annualreviews.org
Various organic reactions, including important synthetic reactions involving C–C, C–N, and
C–O bond formation as well as reactions of biomolecules, are accelerated when the …

Reaction acceleration in electrospray droplets: size, distance, and surfactant effects

BM Marsh, K Iyer, RG Cooks - Journal of The American Society for …, 2019 - ACS Publications
Phenylhydrazone formation from isatin is used to examine the effects on the reaction rate of
(i) electrospray emitter distance from the mass spectrometer (MS) inlet,(ii) emitter tip …

Submicron emitters enable reliable quantification of weak protein–glycan interactions by ESI-MS

EG Báez Bolivar, DT Bui, EN Kitova, L Han… - Analytical …, 2021 - ACS Publications
Interactions between carbohydrates (glycans) and glycan-binding proteins (GBPs) regulate
a wide variety of important biological processes. However, the affinities of most monovalent …

T-matrix methods for electromagnetic structured beams: a commented reference database for the period 2014–2018

G Gouesbet - Journal of Quantitative Spectroscopy and Radiative …, 2019 - Elsevier
T-matrix methods for electromagnetic structured beams mainly encompass Generalized
Lorenz-Mie Theories (GLMTs) which form a set of analytical approaches dealing with the …

Lighting Up at High Potential: Effects of Voltage and Emitter Size in Nanoelectrospray Ionization

JS Jordan, ZM Miller, CC Harper… - Journal of the …, 2023 - ACS Publications
Effects of electrospray voltage on cluster size and abundance formed from aqueous CsI
were investigated with emitter tip diameters between 260±7 nm and 2.45±0.30 μm. Cluster …

Ion mobility–mass spectrometry using a dual-gated 3D printed ion mobility spectrometer

A Hollerbach, PW Fedick, RG Cooks - Analytical chemistry, 2018 - ACS Publications
Described herein is the development of a 3D-printed drift-tube ion mobility spectrometer
(IMS) which operates in the open air and is capable of being coupled to any mass …

Aqueous-microdroplet-driven abiotic synthesis of ribonucleotides

Y Ju, H Zhang, W Wang, Q Liu, K Yu… - The Journal of …, 2022 - ACS Publications
Phosphorylation for ribonucleotide formation is a critical step in the origin of life but has had
limited success due to the thermodynamic and kinetic constraints in aqueous media. Here …

Screening of the Suzuki cross-coupling reaction using desorption electrospray ionization in high-throughput and in Leidenfrost droplet experiments

PW Fedick, K Iyer, Z Wei, L Avramova… - Journal of The …, 2019 - ACS Publications
Suzuki cross-coupling is a widely performed reaction, typically using metal catalysts under
heated conditions. Acceleration of the Suzuki cross-coupling reaction has been previously …

Spatial reorganization of analytes in charged aqueous microdroplets

P Basuri, A Chakraborty, T Ahuja, B Mondal… - Chemical …, 2022 - pubs.rsc.org
Imprinted charged aqueous droplets of micrometer dimensions containing spherical gold
and silver nanoparticles, gold nanorods, proteins and simple molecules were visualized …

Nanopore ion sources deliver individual ions of amino acids and peptides directly into high vacuum

N Drachman, M Lepoitevin, H Szapary… - Nature …, 2024 - nature.com
Electrospray ionization is widely used to generate vapor phase ions for analysis by mass
spectrometry in proteomics research. However, only a small fraction of the analyte enters the …