The non-innocent ligand nature of porphyrins was observed for compound I in enzymatic
cycles of cytochrome P450. Such porphyrin radicals were first regarded as reactive …

Conspectus Since the pioneering work by Thiele and Chichibabin, who synthesized the first
diradicals bridged by phenylene and biphenylene groups in 1904 and 1907, respectively …

As a combination of visible light photoredox catalysis and synthetic organic electrochemistry,
electrochemically-mediated photoredox catalysis emerged as a powerful synthetic …

Developing open-shell singlet (OS) diradicals with high luminescent properties and
exceptional single-molecule magnetoluminescence (ML) performance is extremely …

Persistent covalent-organic framework (COF) radicals hold important applications in
magnetics and spintronics; however, their facile synthesis remains a daunting challenge …

A modular approach for the synthesis of Kekulé diradicaloids is reported. The key step is the
insertion of a carbene, namely, a cyclic (alkyl)(amino) carbene (CAAC), into the C–H bonds …

In this article, some quinoidal p-quinodimethanes compounds that convert partially or
completely to diradicals or biradicaloids are analyzed. The aromatic/quinoidal balance is …

Organic singlet diradicaloids promise application in non-linear optics, electronic devices and
singlet fission. The stabilization of carbon allotropes/cumulenes (C1, C2, C4) by carbenes …

Organic diradicals are uncommon species that have been intensely studied for their unique
properties and potential applicability in a diverse range of innovative fields. While there is a …

Spin–Spin interactions between unpaired electrons in organic radicals are of utter
importance from the viewpoint of molecular magnetism and the development of smart …