Azine‐containing biaryls are ubiquitous scaffolds in many areas of chemistry, and efficient
methods for their synthesis are continually desired. Pyridine rings are prominent amongst …

Abstract The Suzuki–Miyaura coupling is one of the few transition‐metal‐catalyzed C C
bond‐forming reactions that have been used in applications ranging from discovery …

Abstract In Suzuki–Miyaura reactions, anionic bases F− and OH−(used as is or generated
from CO32− in water) play multiple antagonistic roles. Two are positive: 1) formation of trans …

This review describes the recent developments in the field of Suzuki–Miyaura cross‐
coupling reaction, in particular with regard to ligand‐free catalysis. The catalysts outlined …

Most small molecules are highly modular in their constitution, which suggests a potential
general capacity for simple, efficient, and flexible construction through iterative coupling of …

The highly diastereo-and enantioselective title reaction of a range of cyclic imines with
various potassium allyltrifluoroborates most likely proceeds via allylrhodium (I) …

Although potassium organotrifluoroborates (RBF3K) were first explored in the 1960s,[1] it
was not until the mid 1990s that the utility of these air-, moisture-, and thermally stable …

The mechanism of the reaction of trans‐ArPdBrL2 (Ar= p‐Z‐C6H4, Z= CN, H; L= PPh3) with
Ar′ B (OH) 2 (Ar′= p‐Z′‐C6H4, Z′= H, CN, MeO), which is a key step in the Suzuki …

Homogeneous catalysis is a powerful tool in synthetic organic chemistry. Efforts to control
molecular chirality have resulted in major advances in chemical catalysis. 1 Asymmetric …

Palladium-catalyzed Suzuki–Miyaura reactions between aryl boronic acids (Ar'B (OH) 2) and
aryl halides (ArX) to generate ArAr'require a base,[1] such as hydroxide,[2] carbonate, or …