Selective Gas‐Phase Hydrogenation of CO2 to Methanol Catalysed by Metal‐Organic Frameworks

A Dhakshinamoorthy, S Navalón, A Primo… - Angewandte …, 2024 - Wiley Online Library
Large scale production of green CH3OH obtained from CO2 and green H2 is a highly
wanted process due to the role of CH3OH as H2/energy carrier and for producing chemicals …

A review of mechanistic insights into CO2 reduction to higher alcohols for rational catalyst design

Y Sheng, MV Polynski, MK Eswaran, B Zhang… - Applied Catalysis B …, 2023 - Elsevier
The utilization of captured CO 2 for chemical synthesis could play an important role in
reducing CO 2 emissions. Higher alcohols stand out among various products of CO 2 …

Asymmetric Sites on the ZnZrOx Catalyst for Promoting Formate Formation and Transformation in CO2 Hydrogenation

Z Feng, C Tang, P Zhang, K Li, G Li… - Journal of the …, 2023 - ACS Publications
The role of formate species for CO2 hydrogenation is still under debate. Although formate
has been frequently observed and commonly proposed as the possible intermediate, there …

Highly active Pt/In2O3-ZrO2 catalyst for CO2 hydrogenation to methanol with enhanced CO tolerance: The effects of ZrO2

K Sun, C Shen, R Zou, C Liu - Applied Catalysis B: Environmental, 2023 - Elsevier
The supported Pt catalyst is normally not active for CO 2 hydrogenation to methanol at the
presence of CO. Herein, ZrO 2 is added into Pt/In 2 O 3 for CO 2 hydrogenation to methanol …

Engineering nanoscale H supply chain to accelerate methanol synthesis on ZnZrOx

K Lee, PCD Mendes, H Jeon, Y Song… - Nature …, 2023 - nature.com
Metal promotion is the most widely adopted strategy for enhancing the hydrogenation
functionality of an oxide catalyst. Typically, metal nanoparticles or dopants are located …

Active Sites on ZnxZr1–xO2–x Solid Solution Catalysts for CO2-to-Methanol Hydrogenation

S Tada, N Ochiai, H Kinoshita, M Yoshida… - ACS …, 2022 - ACS Publications
Recently, Zn x Zr1–x O2–x catalysts have attracted attention as next-generation CO2-to-
methanol hydrogenation catalysts. In this study, we examined the effect of the Zn content on …

Hollow structured Cu@ ZrO2 derived from Zr-MOF for selective hydrogenation of CO2 to methanol

X Han, M Li, X Chang, Z Hao, J Chen, Y Pan… - Journal of Energy …, 2022 - Elsevier
The development of a highly efficient catalyst for CO 2 activation and selective conversion to
methanol is critical to address the issues associated with the high thermal stability of CO 2 …

Hybrid MOF Template‐Directed Construction of Hollow‐Structured In2O3@ZrO2 Heterostructure for Enhancing Hydrogenation of CO2 to Methanol

WG Cui, Q Zhang, L Zhou, ZC Wei, L Yu, JJ Dai… - Small, 2023 - Wiley Online Library
Direct hydrogenation of CO2 to methanol using green hydrogen has emerged as a
promising method for carbon neutrality, but qualifying catalysts represent a grand challenge …

Design of Flame‐Made ZnZrOx Catalysts for Sustainable Methanol Synthesis from CO2

T Pinheiro Araújo, J Morales‐Vidal… - Advanced Energy …, 2023 - Wiley Online Library
Mixed zinc‐zirconium oxides, ZnZrOx, are highly selective and stable catalysts for CO2
hydrogenation to methanol, a pivotal energy vector. However, their activity remains …

Synergetic Interaction between Single-Atom Cu and Ga2O3 Enhances CO2 Hydrogenation to Methanol over CuGaZrOx

X Han, T Xiao, M Li, Z Hao, J Chen, Y Pan, X Zi… - ACS …, 2023 - ACS Publications
A Cu-based catalyst has prospects for practical use in selective hydrogenation of CO2 to
methanol. But the catalyst's structural complexity renders the elucidation of the nature of …