How softness matters in soft nanogels and nanogel assemblies
Softness plays a key role in determining the macroscopic properties of colloidal systems,
from synthetic nanogels to biological macromolecules, from viruses to star polymers …
from synthetic nanogels to biological macromolecules, from viruses to star polymers …
From femtoseconds to hours—measuring dynamics over 18 orders of magnitude with coherent x-rays
F Lehmkühler, W Roseker, G Grübel - Applied Sciences, 2021 - mdpi.com
X-ray photon correlation spectroscopy (XPCS) enables the study of sample dynamics
between micrometer and atomic length scales. As a coherent scattering technique, it …
between micrometer and atomic length scales. As a coherent scattering technique, it …
The microscopic role of deformation in the dynamics of soft colloids
N Gnan, E Zaccarelli - Nature Physics, 2019 - nature.com
Soft colloids enable the exploration of states with densities exceeding that of random close
packing, but it remains unclear whether softness controls the dynamics under these dense …
packing, but it remains unclear whether softness controls the dynamics under these dense …
Investigation of the yielding transition in concentrated colloidal systems via rheo-XPCS
GJ Donley, S Narayanan, MA Wade… - Proceedings of the …, 2023 - National Acad Sciences
We probe the microstructural yielding dynamics of a concentrated colloidal system by
performing creep/recovery tests with simultaneous collection of coherent scattering data via …
performing creep/recovery tests with simultaneous collection of coherent scattering data via …
Responsive hydrogel colloids: Structure, interactions, phase behavior, and equilibrium and nonequilibrium transitions of microgel dispersions
J Brijitta, P Schurtenberger - Current opinion in colloid & interface science, 2019 - Elsevier
Soft and responsive colloids based on polymer hydrogels have moved into the focus of the
colloid community. This review gives a brief overview of the recent literature on the structure …
colloid community. This review gives a brief overview of the recent literature on the structure …
Probing temperature responsivity of microgels and its interplay with a solid surface by super-resolution microscopy and numerical simulations
Super-resolution microscopy has become a powerful tool to investigate the internal structure
of complex colloidal and polymeric systems, such as microgels, at the nanometer scale. An …
of complex colloidal and polymeric systems, such as microgels, at the nanometer scale. An …
Active glass: Ergodicity breaking dramatically affects response to self-propulsion
We study experimentally the response of a dense sediment of Brownian particles to self-
propulsion. We observe that the ergodic supercooled liquid relaxation is monotonically …
propulsion. We observe that the ergodic supercooled liquid relaxation is monotonically …
Understanding, predicting, and tuning the fragility of vitrimeric polymers
S Ciarella, RA Biezemans… - Proceedings of the …, 2019 - National Acad Sciences
Fragility is an empirical property that describes how abruptly a glass-forming material
solidifies upon supercooling. The degree of fragility carries important implications for the …
solidifies upon supercooling. The degree of fragility carries important implications for the …
Role of Charge Content in the Two-Step Deswelling of Poly(N-isopropylacrylamide)-Based Microgels
R Elancheliyan, G Del Monte, E Chauveau… - …, 2022 - ACS Publications
Poly (N-isopropylacrylamide)-based microgels are soft colloids undergoing a volume phase
transition (VPT) close to ambient temperature. Although widely employed for fundamental …
transition (VPT) close to ambient temperature. Although widely employed for fundamental …
Structure determines where crystallization occurs in a soft colloidal glass
Glass is inherently unstable to crystallization. However, how this transformation occurs while
the dynamics in the glass stay frozen at the particle scale is poorly understood. Here …
the dynamics in the glass stay frozen at the particle scale is poorly understood. Here …