How softness matters in soft nanogels and nanogel assemblies

A Scotti, MF Schulte, CG Lopez, JJ Crassous… - Chemical …, 2022 - ACS Publications
Softness plays a key role in determining the macroscopic properties of colloidal systems,
from synthetic nanogels to biological macromolecules, from viruses to star polymers …

From femtoseconds to hours—measuring dynamics over 18 orders of magnitude with coherent x-rays

F Lehmkühler, W Roseker, G Grübel - Applied Sciences, 2021 - mdpi.com
X-ray photon correlation spectroscopy (XPCS) enables the study of sample dynamics
between micrometer and atomic length scales. As a coherent scattering technique, it …

The microscopic role of deformation in the dynamics of soft colloids

N Gnan, E Zaccarelli - Nature Physics, 2019 - nature.com
Soft colloids enable the exploration of states with densities exceeding that of random close
packing, but it remains unclear whether softness controls the dynamics under these dense …

Investigation of the yielding transition in concentrated colloidal systems via rheo-XPCS

GJ Donley, S Narayanan, MA Wade… - Proceedings of the …, 2023 - National Acad Sciences
We probe the microstructural yielding dynamics of a concentrated colloidal system by
performing creep/recovery tests with simultaneous collection of coherent scattering data via …

Responsive hydrogel colloids: Structure, interactions, phase behavior, and equilibrium and nonequilibrium transitions of microgel dispersions

J Brijitta, P Schurtenberger - Current opinion in colloid & interface science, 2019 - Elsevier
Soft and responsive colloids based on polymer hydrogels have moved into the focus of the
colloid community. This review gives a brief overview of the recent literature on the structure …

Probing temperature responsivity of microgels and its interplay with a solid surface by super-resolution microscopy and numerical simulations

X Shaulli, R Rivas-Barbosa, MJ Bergman, C Zhang… - Acs Nano, 2023 - ACS Publications
Super-resolution microscopy has become a powerful tool to investigate the internal structure
of complex colloidal and polymeric systems, such as microgels, at the nanometer scale. An …

Active glass: Ergodicity breaking dramatically affects response to self-propulsion

N Klongvessa, F Ginot, C Ybert, C Cottin-Bizonne… - Physical review …, 2019 - APS
We study experimentally the response of a dense sediment of Brownian particles to self-
propulsion. We observe that the ergodic supercooled liquid relaxation is monotonically …

Understanding, predicting, and tuning the fragility of vitrimeric polymers

S Ciarella, RA Biezemans… - Proceedings of the …, 2019 - National Acad Sciences
Fragility is an empirical property that describes how abruptly a glass-forming material
solidifies upon supercooling. The degree of fragility carries important implications for the …

Role of Charge Content in the Two-Step Deswelling of Poly(N-isopropylacrylamide)-Based Microgels

R Elancheliyan, G Del Monte, E Chauveau… - …, 2022 - ACS Publications
Poly (N-isopropylacrylamide)-based microgels are soft colloids undergoing a volume phase
transition (VPT) close to ambient temperature. Although widely employed for fundamental …

Structure determines where crystallization occurs in a soft colloidal glass

D Ganapathi, D Chakrabarti, AK Sood, R Ganapathy - Nature Physics, 2021 - nature.com
Glass is inherently unstable to crystallization. However, how this transformation occurs while
the dynamics in the glass stay frozen at the particle scale is poorly understood. Here …