Strong metal–support interaction in heterogeneous catalysts

Z Luo, G Zhao, H Pan, W Sun - Advanced Energy Materials, 2022 - Wiley Online Library
Strong metal–support interaction (SMSI) in supported metal catalysts, typically accompanied
by the formation of encapsulation layers over metal nanoparticles, has drawn intense …

In Situ Kinetic Observations on Crystal Nucleation and Growth

J Li, FL Deepak - Chemical reviews, 2022 - ACS Publications
Nucleation and growth are critical steps in crystallization, which plays an important role in
determining crystal structure, size, morphology, and purity. Therefore, understanding the …

Dynamic interplay between metal nanoparticles and oxide support under redox conditions

H Frey, A Beck, X Huang, JA van Bokhoven… - Science, 2022 - science.org
The dynamic interactions between noble metal particles and reducible metal-oxide supports
can depend on redox reactions with ambient gases. Transmission electron microscopy …

Engineering heterogeneous catalysis with strong metal–support interactions: characterization, theory and manipulation

T Pu, W Zhang, M Zhu - Angewandte Chemie International …, 2023 - Wiley Online Library
Strong metal–support interactions (SMSI) represent a classic yet fast‐growing area in
catalysis research. The SMSI phenomenon results in the encapsulation and stabilization of …

Restructuring of titanium oxide overlayers over nickel nanoparticles during catalysis

M Monai, K Jenkinson, AEM Melcherts, JN Louwen… - Science, 2023 - science.org
Reducible supports can affect the performance of metal catalysts by the formation of
suboxide overlayers upon reduction, a process referred to as the strong metal–support …

Control of metal-support interactions in heterogeneous catalysts to enhance activity and selectivity

TW van Deelen, C Hernández Mejía, KP de Jong - Nature Catalysis, 2019 - nature.com
Metal nanoparticles stabilized on a support material catalyse many major industrial
reactions. Metal-support interactions in these nanomaterials can have a substantial …

Well-defined materials for heterogeneous catalysis: from nanoparticles to isolated single-atom sites

Z Li, S Ji, Y Liu, X Cao, S Tian, Y Chen, Z Niu… - Chemical …, 2019 - ACS Publications
The use of well-defined materials in heterogeneous catalysis will open up numerous new
opportunities for the development of advanced catalysts to address the global challenges in …

Defects Tune the Strong Metal–Support Interactions in Copper Supported on Defected Titanium Dioxide Catalysts for CO2 Reduction

R Belgamwar, R Verma, T Das… - Journal of the …, 2023 - ACS Publications
A highly active and stable Cu-based catalyst for CO2 to CO conversion was demonstrated
by creating a strong metal–support interaction (SMSI) between Cu active sites and the TiO2 …

Strong metal–support interactions on gold nanoparticle catalysts achieved through Le Chatelier's principle

H Wang, L Wang, D Lin, X Feng, Y Niu, B Zhang… - Nature Catalysis, 2021 - nature.com
Strong metal–support interactions (SMSIs) are crucial for the preparation of supported metal
catalysts. A prevailing view is that the redox feature of the metal oxide support is the driving …

Strong Metal–Support Interactions between Pt Single Atoms and TiO2

B Han, Y Guo, Y Huang, W Xi, J Xu… - Angewandte Chemie …, 2020 - Wiley Online Library
Strong metal–support interaction (SMSI) has gained great attention in the field of
heterogeneous catalysis. However, whether single‐atom catalysts can exhibit SMSI remains …