Organosulfur compounds have long played a vital role in organic chemistry and in the
development of novel chemical structures and architectures. Prominent among these …

Asymmetric sigmatropic rearrangement is a powerful organic transformation via substrate-
reorganization to efficiently increase molecular complexity from readily accessible starting …

The development of new sustainable reactions and protocols is essential to fulfill the
growing demands of every branch of organic chemistry for greener synthetic methodologies …

Copper-catalyzed reaction of diazo compounds generates copper carbene intermediates
that undergo diverse transformations. In recent years, the selectivity and efficiency of these …

Here, we report a copper‐catalyzed asymmetric cascade cyclization/[1, 2]‐Stevens‐type
rearrangement via a non‐diazo approach, leading to the practical and atom‐economic …

Among the available methods to increase the molecular complexity, sigmatropic
rearrangements occupy a distinct position in organic synthesis. Despite being known for …

This Feature Article is aimed at highlighting the recent developments in the transition-metal-
free molecular rearrangements involving arynes. The chemistry of arynes has shown …

Covering: from 2000 up to the very early part of 2023 S-Adenosyl-L-methionine (SAM) is a
naturally occurring trialkyl sulfonium molecule that is typically associated with biological …

Conspectus Polysubstituted arenes are prevalent in numerous natural products, medicines,
agrochemicals, and organic functional materials. Among methods to prepare polysubstituted …

Catalysis and synthesis are intimately linked in modern organic chemistry. The synthesis of
complex molecules is an ever evolving area of science. In many regards, the inherent …