Catalytic asymmetric transfer hydrogenation of ketones: recent advances

F Foubelo, C Najera, M Yus - Tetrahedron: Asymmetry, 2015 - Elsevier
In this review, we consider the main processes for the asymmetric transfer hydrogenation of
ketones from 2008 up today. The most effective organometallic compounds (derived from …

Synthesis of half-sandwich ruthenium (II) and iridium (III) complexes containing imidazole-based phosphinite ligands and their use in catalytic transfer hydrogenation …

U Işık, N Meriç, C Kayan, A Kılıç, Y Belyankova… - Journal of …, 2023 - Elsevier
Abstract Two ionic liquids (3-(3‑chloro-2-hydroxypropyl)-1-vinyl-1H-imidazol-3-ium chloride
and 3-(3‑chloro-2-hydroxypropyl)-1‑butyl‑1H-imidazol-3-ium chloride) were prepared from …

Synthesis of some ruthenium (II)–Schiff base complexes bearing sulfonamide fragment: New catalysts for transfer hydrogenation of ketones

S Dayan, NK Ozpozan, N Özdemir, O Dayan - Journal of Organometallic …, 2014 - Elsevier
Four new ruthenium (II) complexes [RuCl (1–4)(p-cymene)](1–4= N-(3-(2-
hydroxybenzylideneamino) phenyl) benzenesulfonamides) were synthesized from [RuCl 2 …

(Pyridyl) benzoazole ruthenium (II) and ruthenium (III) complexes: role of heteroatom and ancillary phosphine ligand in the transfer hydrogenation of ketones

AO Ogweno, SO Ojwach, MP Akerman - Dalton Transactions, 2014 - pubs.rsc.org
The synthesis and structural characterization of ruthenium complexes supported by 2-(2-
pyridyl) benzoazole ligands and their evaluation as catalysts in the transfer hydrogenation of …

Cyclometalated ruthenium (II) carbonyl complexes containing 2-(biphenylazo) phenolate ligands: Synthesis, structure, DFT study and catalytic activity towards …

M Ramesh, MD Kumar, M Jaccob, B Therrien… - Inorganica Chimica …, 2018 - Elsevier
(Biphenylazo) phenol ligands with various functional groups at the para-position of the
phenol moiety (R= CH 3, H 2 L 1; R= OCH 3, H 2 L 2; R=(CH 3) 3 C, H 2 L 3; R= Cl, H 2 L 4) …

The first application of C2-symmetric ferrocenyl phosphinite ligands for rhodium-catalyzed asymmetric transfer hydrogenation of various ketones

B Ak, M Aydemir, F Durap, N Meric, A Baysal - Inorganica Chimica Acta, 2015 - Elsevier
Homogeneous catalysis has been responsible for many major recent developments in
synthetic organic chemistry. The combined use of organometallic and coordination …

Well designed iridium-phosphinite complexes: Biological assays, electrochemical behavior and density functional theory calculations

K Rafikova, N Meriç, NE Binbay, V Okumuş… - … Acta Part A: Molecular …, 2024 - Elsevier
Mononuclear phosphinite Iridium complexes based on ferrocene group have been prepared
and characterized by various spectroscopic techniques. The complexes were subjected to …

Novel Mononuclear Metal-Phosphinite Compounds And Catalytic Performance In Transfer Hydrogenation Of Ketones

U Işık, N Meriç, M Aydemir - Middle East Journal of Science, 2022 - dergipark.org.tr
Since the obtained chiral alcohols are rather useful as well as biologically active
compounds, reduction of ketones to their respective alcohols is a crucial topic in synthetic …

Enantioselective transfer hydrogenation of various ketones with novel efficient iridium (III) ferrocenyl-phosphinite catalysts

N Meric, M Aydemir - Journal of Organometallic Chemistry, 2016 - Elsevier
The asymmetric reduction of prochiral ketones is a pivotal reaction for the preparation of
chiral alcohols which form an extremely important class of intermediates for fine chemicals …

Novel pyrazolylphosphite–and pyrazolylphosphinite–ruthenium (ii) complexes as catalysts for hydrogenation of acetophenone

G Amenuvor, C Obuah, E Nordlander, J Darkwa - Dalton Transactions, 2016 - pubs.rsc.org
The new compounds and potential ligands 2-(3, 5-di-tert-butyl-1H-pyrazol-1-yl)
ethyldiphenlyphosphinite (L1), 2-(3, 5-di-tert-butyl-1H-pyrazol-1-yl) ethyldiethylphosphite …