C–H functionalization has been emerging as a powerful method to establish carbon–carbon
and carbon–heteroatom bonds. Many efforts have been devoted to transition-metal …

C–H bonds are ubiquitous in organic molecules. Homogenous gold-catalyzed direct
functionalization of unsaturated C–H bonds has emerged as a powerful method in our …

Density functional theory calculations were applied to study four previously published metal-
catalyzed [2, 3]-rearrangements from onium ylide intermediates, in pursuit of generalizations …

Phenothiazine is an important structural motif in pharmaceuticals and advanced functional
organic materials. However, the C− H functionalization reaction of N‐protected …

The first Doyle–Kirmse reaction on alkynyl diazoacetates using allyl/propargyl sulfides is
reported. The development provides diversified 1, 5-enyne and 1, 4-allenyne thioaryl …

In this work, we studied the wavelength (520 or 350 nm) dependence of the photochemical
decomposition of 1-phenyl-1-diazopropane (PDP) and 1-phenyl-1-propyl diazirine (PED) by …

The asymmetric Doyle–Kirmse reaction has become increasingly important in the
construction of chiral sulfides, especially for those with quaternary carbon stereocenters …

Onium ylides are reactive intermediates that undergo versatile chemical transformations to
give structurally interesting compounds. Rearrangement reactions of onium ylides are of …

As a common and integral feature of many natural products, thiocarboxylates play an
important role in biologically or pharmaceutically active compounds. Thiocarboxylates often …

A gold catalyzed formal intermolecular [2+ 3] cyclo-coupling of 1, 3-enynes with phenols was
developed to prepare dihydrobenzofuran derivatives with the addition of 2, 6 …